神府煤煤岩组分浮选工艺及动力学研究.pdf

采用了经典一级动力学模型[ε 82.01×( 1-exp(-0.74t))] 与二级动力学模型[ε 2 112.90 ×0.53t/(100 + 112.90×0.53t)]对浮选实验结果进行了动力学拟合计算，结果表明一 级浮选模型可较好地模拟神府煤的浮选过程。对药剂机理进行分析表明两种捕收剂共同 作用时会出现层叠型吸附，无机调整剂与捕收剂混合作用时，会发生穿插型吸附。 关 键 词：神府煤；煤岩组分；浮选；改性；动力学 研究类型：应用研究 Subject: The Study on flotation process and dynamics of the maceral from Shenfucoal Specialty : Mineral Processing Engineering Name : GongLiang (Signature) Instructor: YangZhiyuan (Signature) ABSTRACT Inertinite content of Shenfu coal is commonly high,which has adverse effect on gasification and liquefaction of such coal. We can separate macerals from Shenfu coal by flotation method, which include vitrinite and inertinite.Shenfu coal can realize high-efficiency utilization that vitrinite is used for liquefaction and gasification and inertinite used for the preparation of carbon materials. The properties of Shenfu coal and macerals were studied deeply through the pore structure test,FTIR, maceral analysis,coal interface performance testing methods in the paper. It found that great difference on pore structure, surface functional groups, wettability ,surface potential and grindability,and provide a theoretical foundation for subsequent separation of macerals.To achieve the full dissociation of the different macerals, the selective crushing of its was studied by using microwave pretreatment in the paper, the dissociation of different macerals was increased significantly after the microwave introducing, rich vitrinite content in raw coal after radiation by 31.83%. SEM analysis shows that microwave promote fusain crack growth. Based on difference on wettability and surface electrical of macerals, this paper has completed flotation separation of experimental study in flotation cell (1.5 L).For flotation separation process single factor analysis of macerals, the best experimental res