并列型静电纺丝法制备扭曲螺旋结构的复合微_纳米纤维与表征.pdfVIP

39 2 Vol39 No2 2011 2 NEW CHEM ICAL MATERIALS 39 / 饶 丹 李从举* ( 1. 北京服装学院材料科学与工程学院, 北京100029; 2. 北京市服装材料研究开发与评价重点实验室, 北京 100029) 采用 列型静电纺丝法成功制备出新型的扭曲螺旋结构的复合微/ 纳米纤维主要使用扫描电镜Sm ile View 图像分析软件对样品的微观形貌及结构进行了表征和分析分析结果表明, 高收缩性聚酯弹性体T PEE 和相对收 缩率较低的PBT ,在 列型电纺过程中因断裂伸长率不同产生不同程度的收缩, 从而形成三维扭曲螺旋结构的复合纤维 所得纤维是表面具有刺状突起的扭曲螺旋结构的复合微/ 纳米纤维, 纤维直径约 1m, 表面刺状突起约300nm 静电纺丝, 列型, 螺旋, 复合, 微/ 纳米纤维 Preparation and characterization of selfcrimp composite nanofibers via sidebyside electrospinning technique Rao Dan Li Congju ( 1. School of Material Science and Engineering, Beijing Institute of Fashion T echnology, Beijing 100029; 2 . Beijing Key Laboratory of Clothing Materials R D and Assessment, Beijing 100029) Abstract New ly selfcrimp com posite nanofibers were successfully synthesized via sidebyside electrospinning technique. The morphology and microstructure of the com pound nanofibers w ere studied and analyzed by scanning electron microscope ( SEM) and Smile View . The results show ed that thermoplastic ester elastomer T PEE and polybutylece tereph thalate PBT, as different shrinkage, caused different shrink and formed 3D selfcrimp composite nanofibers in sidebyside electrospinning. Nanofiber had obvious project ion with the diameter of 300nm on its surface and the diamet er of composite nanofiber was about 1m. Key words electrospinning, sidebyside, selfcrim p, composite, nanofibers / , , , ,