林业世界—适于木本植物油脂的催化剂研究.pdfVIP

World Journal of Forestry 林业世界, 2012, 1, 1-7 Published Online April 2012 (/journal/wjf) Study of Catalyst Appliable for Woody Plant Oil: Nano Solid Superacid Catalyzing the Esterification of Free * Fatty Acid 1,2# 2 3 2 1 2 Xuejun Zhang , Wenkun Zhang , Bo Li , Hanmei Ouyang , Rong Zhou , Hui Zhong 1School of Chemistry and Chemical Engineering, Guizhou University, Guiyang 2Guizhou Province Key Laboratory of Fermentation Engineering Biological Pharmacy, Guizhou University, Guiyang 3Southwest Guizhou Kangda Bioenergy Technology Co., Ltd., Xingyi Email: #xzhang203@ Received: Mar. 29th, 2012; revised: Apr. 13th, 2012; accepted: Apr. 16th, 2012 Abstract: Generally woody plant oil bears a higher acid value than the oil from herbaceous plant. Basic catalyst will lead to soap reaction in transesterification of oil. Tow step method divides the production of bio- diesel into the esterification of free fatty acid and the transesterification of oil, which improves resource utilization greatly and broadens sources of oil, contributing to a low cost. Sin is a few metals by which solid superacid can be prepared. The present paper used nanocrystal of SnO2 doped with Sb as carrier to superfi- cially sulfate on it. Nano-catalyst SO2 @Sb-SnO2 calcined at 330˚C for 3 h is a solid superacid with a 4 strong acidy, Hammett function H0 ≥ –14.5, stronger than 100% sulfuric acid (–11.9) near to 1000 times. The