电喷雾电离-串联质谱法测定纺织皮革产品中4,4-二氨基二苯醚.pdfVIP

4,4 1,2 2 1 1 , , , (1. , 453003; 2. , 100081) : 在不需要色谱分离的前提下,应用电喷雾电离串联质谱法(ESIMS/MS) 对纺织品中 偶氮染料还 产物4,4二氨基二苯醚进行测定在MS/MS 中,选择电喷雾离子源, 以正离子扫 描,选择离子监测模式和二级选择反应监测模式对4, 4二氨基二苯醚进行定性和定量检测以 [M+ H](m/ z 201)为母离子, 选择其二级离子中碎片离子[M+ H- NH3 ](m/ z 184)和[M+ H- - 1 - 1 C6 H7 N](m/ z 108)为子离子方法的检出限(19S/ N ) 为70 ng L 以1 ng L 4,4二氨基 二苯醚溶液进样2L,平行测定9次,峰面积测定值的相对标准偏差为1.7 : 电喷雾电离; 串联质谱; 4,4二氨基二苯醚 : O657.7 : A :2011) Electrospray IonizationMS/ MS Determination of 4,4Diamino Diphenyl Oxide in Textiles and Leathers 1, 2 2 1 1 ZH NGYan , Y NG Chengdui , Y NG Li , QI OMeiying ( 1. Dep t. of Chem . and Chem. Eng. , H enan I nstitute of Science and T echnology , X in iang 453003, China; 2. D ep artment of Chem . , Tsinghua Univ ers ity , Beij ing 100084, China) bstract: Electrospray ionizationtandem mass spectrometry ( ESIMS/MS) was applied to the detection of 4, 4diamino diphenyl oxide reduced from various azo dyes in textiles and leathers, without chromatographic separation. In the MS/ MS analysis, ESI was used as ion source, and modes of SIM and SRM with positive ion scanning were taken for qualitative and quantitative analysis of 4, 4diamino diphenyl oxide. The [ M+ H] (m/ z 201) was taken as the mother ion, and the fragment ions [M+ H- NH ] (m/ z 184) and [ M+ H- C H N] (m/ z 3 6 7 - 1 108) were taken as daughter ions. Limit of detection ( 19S/ N ) found for the method was 70 ng L . Precision of