动电位阳极沉积法制备锰氧化物薄膜及其.pdfVIP

動電位陽極沉積法製備錳氧化物薄膜及其 擬電容行為* Pseudo-capacitive Properties of Manganese Oxide Films as Prepared * by Potentiodynamic Anodic Deposition 1 2 3 1 2 3 Y.T. Hsiao C.H. Liang C.S. Hwang It is noticeable that a sup ercapacitor has such a high st ability and sp ecific capacit ance (SC) that are deemed as most suitable for a backup device for electronic product s. Manganese oxide is one of the promising electrode materials for the supercapacitor. Th is stu dy tr ied t o pr ep ar e the m anganese oxide f ilm s u sin g p ot ent iody n am ic an odic dep o sit ion under differ ent dep osit ion r at es. We u sed R am an Raman FE-SEM scatt er ing sp ectr a and a f ield-em ission scann ing electr on m icr oscopy (FE - SEM) t o det er m in e th e 0.1M Na SO 25 microstructures and chemical comp osition s of the 2 4 m an gan e se ox ide f ilm s . Th e p seu do - cap acit ive p r op er t ie s of t h e m an g an e se ox id e f i lm s w er e determined by cyclic voltammetry (CV) in the range - 1 ○ 100 mVs 0.0-1.0V (vs. SCE) in 0.1M Na SO solution at 25 C. 2 4 2 19 Fg- 1 The porous and nano fiber structures were obtained (600 mVs- 1) for the manganese oxide film deposited at a deposition