乙二醇吸收羰基硫实验及机理研究.pdfVIP

摘 要 羰基硫是存在于石油炼制气、裂解气和煤气中的一种有毒的有机硫化物，工业 生产中该化合物的存在不仅会腐蚀设备和毒害生产过程中的催化剂，而且会给环境 造成严重的污染。乙二醇作为一种廉价的羰基硫吸收剂，具有较大的开发前景；但 由于羰基硫在乙二醇中的溶解度较小，清除困难。因此，研制和开发一种与乙二醇 复配效果较好的脱硫剂具有重要的现实意义和经济效益。 本文建立了定量分析羰基硫的气相色谱法，该法不仅方便、准确，而且能同时 测定多种硫化物，适用于生产和环境控制分析。研究结果表明，羰基硫的峰面积相 对标准偏差为 1.5%，羰基硫的峰面积与羰基硫的绝对量的双对数线性关系较好，相 关系数为 0.9996 。 对不同浓度、不同温度下乙二醇-水体系吸收羰基硫气体的能力实验进行了考 察。研究发现，在乙二醇溶剂中加入一定量的水后能明显提高乙二醇溶剂吸收羰基 硫的能力；当乙二醇-水体系的体积浓度为 50%、温度为 313.15K 时，该体系对羰 基硫的吸收能力达最大 15.7421 mg/L。 本文还对乙二醇-水体系吸收羰基硫气体的吸收机理进行了探讨，并利用紫外、 红外、质谱、核磁等手段对吸收前、后的溶液体系进行表征，发现水的加入减弱了 乙二醇之间的氢键作用，使得溶液能够以氢键作用与羰基硫结合。 关键词：脱硫；乙二醇；羰基硫；氢键作用 Abstract Carbonyl sulfide is a toxic gas which is presented in petroleum, coal refinery gas and coal gasification stream, and it is corrosive to pipelines and other processing equipment, and is also pollution to the environment. Ethylene glycol is a cheap absorbent of carbonyl sulfide, but carbonyl sulfide is difficult to be absorbed because of its low solubility in ethylene glycol. Thus, it is significant to develop a better absorbent to carbonyl sulfide. In this paper, gas chromatography method has been developed to determine content of sulfur compounds. The results showed that the relative standard derivation of peak area is 1.5%..The two logarithmic value for peak area and the absolute value of COS is linear correlated,and the correlation coefficient is 0.9996. The absorption capability of ethylene glycol-water sestem to carbonyl sulfide was studied under different temperature and different concentration. The results showed that the absorption capability of ethylene glycol was improved when water was added into pure ethylene glycol. The maximum efficiency obtained reached to 15.7421mg/L under the conditions as follows: the con