气固吸附体系中吸附势理论的研究.pdfVIP

气固吸附体系中吸附势理论的研究 郭 璞 刘 娟 李 明 （同济大学化学系，上海200092 ） 摘要：吸附势理论广泛应用于微孔吸附剂表面吸附现象的研究。本文采用容积法测定了甲烷和氮气在微孔 活性炭上的吸附平衡数据,温度区间控制在253～313K,压力范围为0～3MPa 。以吸附势理论为指导,绘制出 吸附特征曲线,考察了各种计算吸附相虚拟饱和蒸汽压的方法对吸附平衡预测结果的影响。研究表明,吸附 势理论可以在较宽的温度范围内描述甲烷及氮气的吸附平衡。通过热力学推导，提出了一种新的计算虚拟 饱和蒸汽压的方法，通过与传统方法的比较，表明该方法同样适用于临界温度以上的虚拟饱和蒸汽压的计 算。 关键词：吸附势理论；虚拟饱和蒸汽压；热力学 中图分类号： O647.31 文献标识码：A Studies on Adsorption Potential Theory of Gas-solid Adsorption System GUO Pu, LIU Juan, LI Ming (Department of Chemistry ，Tongji University ，Shanghai 200092，Shanghai，China) Abstract: Adsorption potential theory has been widely applied to investigate gas adsorption equilibria on microporous adsorbents. The adsorption equilibrium data of methane and nitrogen on the activated carbon were measured by a volumetric method. The experiments were carried out under supercritical conditions with temperature range of 253.2-313.2 K and pressure range of 0-3MPa.This theory could predict the adsorption equilibrium of methane and nitrogen on the activated carbon in widely temperatures range effectively. The predicting accuracy is considerably sensitive to the quasi-saturated vapor pressure. A new method calculating quasi-saturated vapor pressure was presented according to thermodynamics derivation. Compared with the literatures methods, it was proven suitable on supercritical temperature region. Key words: adsorption potential theory; quasi-saturated vapor pressure; thermodynamics 引 言 以Dubinin-Radushkevich (DR)方程和Dubinin-Astakhov (DA)方程为主的吸附势理论 已被广泛应用于研究气体在微孔吸附剂(如沸石和活性炭等)中的吸附平衡, 是目前描述微 孔吸附剂表面气体吸附现象的主要方法[1-3] 。该理论将气体分子与吸附剂表面原子之间的作 用力简化为与温度无关的色散力，建立起吸附相体积与吸附势的关系曲线，将同种吸附剂在 不同温度下的吸附等温线用一条吸附体系的特征曲线来表示。这一结论得到了大量实验数据