聚丙烯纤维化学接枝改性增强水泥基复合材料界面结合_李启金.pdfVIP

复 合 材 料 学 报 A c t a M a t e r i a e C o m p o s i t a e S i n i c a 聚丙烯纤维化学接枝改性增强水泥基复合材料的界面结合 李启金，李国忠* （济南大学材料学院建筑材料制备与测试技术山东省重点实验室，济南 250022 ） 摘 要：以过氧化苯甲酰（BPO ）为引发剂，采用二步化学接枝法对聚丙烯纤维进行接枝丙烯酸改性，利用正交 分析法研究了引发温度、BPO浓度、接枝温度、接枝时间及丙烯酸(AA ）浓度对纤维接枝率的影响，并评价了改 性前后纤维与水泥基体的界面结合性能。结果表明：上述因素对纤维接枝率的影响大小为引发温度＞BPO浓度＞ -2 接枝时间＞接枝温度＞AA浓度，最佳反应条件为引发温度90℃，BPO 4.50 ×10 mol/L ，接枝时间60min，接枝温 度75℃，AA 1.4mol/L ，此时纤维接枝率达13.12%；经化学接枝改性后，聚丙烯纤维表面亲水性和粗糙度增大， 与水泥基体的界面结合得到增强，纤维掺量为0.05% （体积分数）时，聚丙烯纤维增强水泥砂浆的抗开裂性能比 增大了26.6% ，抗塑性收缩开裂性能显著增强。 关键词：聚丙烯纤维；化学接枝改性；水泥基复合材料；界面结合；抗塑性收缩开裂 Surface modification on polypropylene fibers by chemical grafting methods to reinforce the interfacial bonding of cement-based composites * LI Qijin, LI Guozhong （Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, School of Materials Science and Engineering, University of Jinan, Jinan 250022, China ） Abstract: With benzoyl peroxide (BPO) as initiator, the surface of polypropylene (PP) fibers was modified with acrylic acid by two step-chemical grafting methods. The effects of initiation temperature, concentration of BPO, grafting temperature, grafting time and concentration of AA on the grafting degree of PP fibers were studied with orthogonal analysis method, and the interfacial bonding between cement matrix and PP fibers before and after modification was