亚熔盐法法回收赤泥研究.pdfVIP

亚熔盐法回收赤泥的研究 钟莉1, 2 1 1 ，张亦飞 ，张懿 (1. 中国科学院过程工程研究所，北京 100190 ，中国； 2. 中国科学院研究生院，北京 100049 ，中国) 摘 要：本文采用亚熔盐法对赤泥中氧化铝和氧化钠的回收进行了研究，实验通过回 收氧化铝后使赤泥中的氧化铝含量降至 4.19%，单程回收率达到 88.05%；对回收氧化铝后 的赤泥进一步脱钠后，最终赤泥中A/S 和 N/S 相应降到 0.17 和 0.06，有效减少了紧缺资源 铝土矿的资源浪费和环境污染，使最终赤泥可更大配料比的用于生产水泥，另外，回收氧化 铝和氧化钠后的终赤泥型貌呈现表面疏松多孔的颗粒状，具有制备成修复环境污染的吸附剂 等综合利用前景。 关键词：赤泥；亚熔盐；氧化铝；氧化钠；回收 中图分类号：TQ133.1  Research on the purification of red mud by Sub‐molten Salt  1, 2 1 1 ZHONG Li , ZHANG Yi-fei , ZHANG Yi (1. Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100080, China; 2. Graduate University of Chinese Academy of Sciences, Beijing 100049, China) Abstract: This paper researches on the purification of red mud by Sub-molten Salt. The mass percentage of alumina in the red mud was reduced to 4.19% and 88.05% of the alumina was purified from the red mud, after that the purification of sodium oxide was investigated. As a result of it, the molar ratio of alumina to silicon dioxide, i.e. A/S, in the final red mud decreases to 0.17 and the molar ratio of sodium oxide to silicon dioxide, i.e. N/S, decreases to 0.06. By doing this, we can make good use of the alumina mineral resources and reduce the pollution to environment by alumina industry, for example the final red mud can be used in the produce of the cement in higher mass ratio than before and it can be used as many kinds of sorbents to harness the environmental pollution because of its lacunaris configuration. Key words: red mud; sub-molten salt;alumina; sodium oxide; purification 基金项目：国家重点基础研究发展计划（973 计划）（编号：2007CB613501 ） 赤泥的回收与利用一直是氧化铝行业面临的世界性难题，目前全世界每年产生约5000 作者简介：钟莉（1981-），博士研究生，绿色过