铜离子配位儿茶酚分子印迹膜合成.docVIP

论文编码 首都师范大学本科毕业论文 铜离子配位儿茶酚分子印迹膜的合成 The Synthesis of copper()- Catechol complex Molecularly Imprinted Polymer Membranes 作 者 徐哲 院 系 化学系 专 业 应用化学 学 号 1060700035 指导老师 　 朱若华 完成日期 2010年 5月 20日 中文提要 儿茶酚是重要的化工原料，但对人体有很大毒性，对环境有一定污染。分子印迹技术是近年来发展起来的新的研究领域，有很大的研究前景和应用空间。本实验采用二甲基丙烯酸乙二醇酯（EDMA，交联剂）、甲基丙烯酸缩水甘油酯 （GMA、支撑膜的单体）、正丙醇（致孔剂）、1,4—丁二醇（致孔剂）、N-溴代丁二酰亚胺偶氮二异丁腈 用乙二胺四乙酸二钠（EDTA的二钠盐）溶液将儿茶酚与铜的金属配合物洗脱下,来并采用紫外可见光吸光光度的方法，测定儿茶酚的吸光光度，检验儿茶酚分子印迹膜的吸附效果。实验结果表明在一定浓度铜离子存在下，分子印迹膜对模板分子儿茶酚表现出一定的吸附性。此方法十分简单，并易于操作。 关键字:分子印迹膜 儿茶酚-铜配合物 紫外光引发聚合 紫外可见光吸光光度法 Abstract Catechol is an important chemical raw material,but it is very toxic for human body, and can make environmental pollution. Molecular imprinting technology as a new areas of research developed in recent years, has great prospects for the study and application. In this study, using ethylene glycol dimethacrylate (EDMA, crosslinking agent), glycidyl methacrylate (GMA, supporting membrane monomer), n-propanol (porogen), 1,4 - succinic ethanol (porogen), N-bromo succinimide (NBS, brominated agent), azobisisobutyronitrile (AIBN, Photoiniferter), the base membrane was synthesis. The copper(II)- catechol complex molecularly imprinted polymer membranes was synthesized using complexes of catechol and copper as the template, imidazole ethyl acrylate as the monomer by UV polymerization method. Conditions for the synthesis were studied and optimized in detail, such as brominated agent and crosslinker ratio, the amount of copper and catechol ratio as well as the lighting equipments. EDTA solution was used to elution the metal complexes of catechol and copper (II), determinating the absorbance of catechol and adsorption of molecular imprinted membrane to catechol. Experimental results show that in the presence of copper ion, molecular imprinted membrane for the template molecule catechol show some adsorption. This method is simple and easy to operate. Keywords: Molecular