基于富勒烯和噻吩聚合物本体异质结太阳电池71458.pdfVIP

20 9 化 学 进 展 Vol. 20 No. 9 2008 9 PROGRESS IN CHEMISTRY Sep. , 2008 基于富勒烯和噻吩聚合物的本体异质结太阳电池* 姜鸿基 邓先宇 黄 维* * ( 南京邮电大学信息材料与纳米技术研究院江苏省有机电 与信息显示重点实验室 南京210046) 随着全球能源需求量的逐年增加, 对可再生能源的有效利用成为解决日益严重的能源危机的 主要手段, 太阳电池被认为是清洁可再生新能源的代表之 一基于富勒烯和噻吩聚合物的本体异质结太阳 电池因其制备简单成本低廉重量轻及可制成柔性器件等优点, 近年来受到广泛关注, 成为目前太阳电池的 重要发展方向经过努力, 该种太阳电池的光电转化性能得到了 一定提高, 最高能量转化效率已达到 65% , 但是与无机半导体硅和染料敏化太阳电池相比还有 一定差距本文从材料合成的角度, 简要综述了 近年来国内外在基于富勒烯和噻吩聚合物的本体异质结太阳电池方面所取得的最新研究进展, 并对下一步 需要研究的热点问题作了展望 太阳电池 噻吩聚合物 富勒烯 受体 给体 效率 : O631. 2; TN383; TB324 : A : 1005281X( 2008) Bulk Heteroj unction Solar Cell Based on Fullerene and Polythiophene * * Jiang Hongj i Deng X iany u H uang Wei ( Jian su Key Lab for Or anic Electronics Information Displays, Institute of Advanced Materials, Nanjin University of Posts Telecommunications, Nanjin 210046, China) Abstract Or anic and polymer photovoltaic cells are becomin an extremely active research area to meet the ur ent need for clean and renewable ener y mana ements due to their potential applications as flexible, low cost and solution processable ener y sources. The photophysics of such photoactive devices is based on the photoinduced char e transfer from donortype semiconductin conju ated polymers to acceptortype conju ated polymers or acceptor molecules such as buckminsterfullerene or C . At present, socalled bulk heterojunction structures based on blends of a polymeric donor of 60 polythiophene and the soluble fullerene derivative [ 6, 6]phenyl C61 butyric acid methyl ester ( PCBM) as an acceptor component represent