聚氯乙烯的热解特性和热解动力学研究.pdfVIP

第 35卷 第 4 期 燃 　料 　化 　学 　学 　报 V o l. 35 N o. 4 2007 年 8 月 J ou rna l of Fue l C hem istry and Techno logy A ug. 2007 文章编号 : 0座机电话号码 2007 0座机电话号码 聚氯乙烯的热解特性和热解动力学研究 孙庆雷 , 时新刚, 林云良, 祝 　贺 , 王 　晓, 程传格 , 刘建华 山东省科学院 山东省分析测试中心 , 山东 济南 　2500 14 关键词 : 聚氯乙烯; 热解; 动力学 中图分类号 : TQ 325. 3　　文献标识码 : A P y r o ly s is o f p o ly v in y l ch lo r id e a n d it s k in e t ic s a n a ly s is SUN Q ing le i, SH I X in gang, L IN Yun liang, ZHU H e, W AN G X iao, CH EN G C hu an ge, L IU J ian hua Shandong Ana lys is and Test C en ter, Shandong A ca dem y of Sc ience, J inan　2500 14, C h ina A b s t r a c t : The effec t of p y ro ly sis tem p era tu re on y ie ld of p o lyv iny l ch lo ride PV C p y ro ly sis cha r w as sy stem a tica lly investigated in a fixedb ed reac to r. Th e th erm og rav im e tric charac teristics of PV C w ere a lso investigated. Th e p y ro ly sis k in etics w as ana lyzed by C oa tsR edfern in teg ra tion m e thod. Th e f ixed bed resu lts show that w ith increasing p y ro ly sis tem p eratu re, th e y ie ld of char du ring p y ro ly sis of PV C decreases. Th e TG /D TG resu lts show that w ith increasing tem p e ratu re, the y ie ld of vo la tile m atte r increased. The TG /D TG cu rves of PV C p y ro l y sis sh ifts to h igh er tem p era tu re w ith inc reasing heating rate. Th e k in etic resu lt illu strates that the p y ro ly sis can be d iv ided in to tw o stages based on d iffe ren t ac tivation ene rg ies. Th e f irst stage has low er ac tiva tion en ergy abou t 50 kJ /m o l, and that of the second stage is abou t 245 kJ /m o l. K e y w o r d s : PV C; p y ro ly sis; k in etics 　　随着聚氯乙烯的