3金刚石膜电极电化学氧化提高废水可生化性的研究.pdfVIP

中国环境科学 2009,29(12) ：1255~1259 China Environmental Science 金刚石膜电极电化学氧化提高废水可生化性的研究 * 庞雅宁,赵国华 ,刘 磊,高俊侠( 同济大学化学系,上海 200092) 摘要：采用掺硼金刚石膜电极 电化学氧化的方法提高 -氯苯酚废水的可生化性与钛基钌铱氧化物电极 进行对比研究了该方 (BDD) 2 , (DSA) , 法的机理.结果表明,BDD 电极电化学氧化 2.0h 后,BOD5/CODCr 值达到 0.42,有效提高了废水的可生化性,而 DSA 电极电化学氧化 2.0h 后,BOD5/CODCr 值仅为0.24.机理研究表明, 由于BDD 电极具有高的析氧电位,可产生大量的羟基自由基( OH),能够使2-氯苯酚的苯环充分⋅ 开环形成草酸、顺丁烯二酸等易生化处理的中间产物从而使可生化性提高而 电极的析氧电位较低产生羟基自由基的能力较差不 , , ; DSA , , 能有效地提高废水的可生化性. 关键词：金刚石膜电极；2-氯苯酚；电化学氧化；可生化性 中图分类号：X703.1 文献标识码：A 文章编号：1000-6923(2009)12-1255-05 Enhanced biodegradability of wastewater with electrochemical oxidation on boron-doped diamond anode. PANG * Ya-ning, ZHAO Guo-hua , LIU Lei, GAO Jun-xia (Department of Chemistry, Tongji University, Shanghai 200092, China). China Environmental Science, 2009,29(12)：1255~1259 Abstract ：Electrochemical oxidation on boron-doped diamond (BDD) anode was used as pretreatment for 2-chlorophenol wastewater to improve its biodegradability, using DSA electrode as a comparison. And the mechanism was also discussed. Afeer 2h electrochemical oxidation of 2-chlorophenol wastewater on BDD electrode, BOD5/CODCr reached 0.42, while the value only reached 0.24 on DSA electrode. This was closely related with the properties of the electrode. BDD electrode had a high oxygen evolution potential, and many hydroxyl radicals were generated in the solution. This led to that 2-chlorophenol was fully ring-opening, forming intermediates such as oxalic and maleic acids which were easy to be biodegraded. Thus, the b