分子印迹聚合物膜离子选择性电极技术检测海水中的有机污染物(论文).docVIP

分子印迹聚合物膜离子选择性电极技术检测海水中的有机污染物 梁荣宁, 宋德安，张锐明，秦 伟* 中国科学院烟台海岸带研究所，264003，烟台 E-mail: wqin@yic.ac.cn 离子选择性电极检测技术由于其具有操作简单、成本低廉以及选择性高等诸多优点，因而广泛应用于工业分析、临床化验、环境监测等领域。海水中有机污染物如有机磷、有机氯农药等的存在形态，主要以电中性分子的形式存在。然而，长期以来采用离子选择性电极电位法检测电中性有机分子一直是困扰分析化学家的一个难题，因为电极电位响应的先决条件是待测物必须为带电荷的离子。 分子印迹聚合物是近年发展起来的具有分子识别能力的新型功能材料，可广泛用于亲和色谱、固相萃取、传感器等领域。[1] Jiawang Ding and Wei Qin,* Chem. Comm, 2009, 971-973 [2] Rongning Liang, Ruiming Zhang, and Wei Qin,* Sens. Actuat. B, 2009, 141, 544-550 [3] Rong-Ning Liang, De-An Song, Rui-Ming Zhang, and Wei Qin,* Angew. Chem. Int. Ed, 2010, 49, 2556-2559 [4] Jiawang Ding and Wei Qin,* J. Am. Chem. Soc, 2009, 131, 14640-14641 Polymeric membrane Ion-Selective Electrodes Based on Molecularly Imprinted Polymers for Detection of Organic Pollutants in Seawater Rong-Ning Liang, De-An Song, Rui-Ming Zhang,* Wei Qin Yantai Institute of Coastal Zone Research, CAS, 264003, Yantai Polymeric membrane ion-selective electrodes for sensitive potentiometric detection of neutral organic pollutants in seawater are present. The proposed method provides a general sensing principle for selective and sensitive detection of neutral species using ion-selective electrodes (ISEs). The strategy will be expected to make a new pathway to use ISEs for monitoring organic pollutants in seawater, or other environmental samples.