Pyroelectricity and Optical Second Harmonic Generation in Polyvinylidene Fluoride Films教程.pdf

PYROELECTRICITY AND OPTICAL SECOND HARMONIC GENERATION IN POLYVINYLIDENE FLUORIDE FILMS J. G. Bergman, J. H. McFee, and G. R. Crane Citation: Appl. Phys. Lett. 18, 203 (1971); doi: 10.1063/1.1653624 View online: /10.1063/1.1653624 View Table of Contents: /resource/1/APPLAB/v18/i5 Published by the American Institute of Physics. Additional information on Appl. Phys. Lett. Journal Homepage: / Journal Information: /about/about_the_journal Top downloads: /features/most_downloaded Information for Authors: /authors Downloaded 19 Sep 2012 to 43. Redistribution subject to AIP license or copyright; see /about/rights_and_permissions APPLIED PHYSICS LETTERS VOLUME 18, NUMBER 5 1 MARCH 1971 PYROELECTRICITY AND OPTICAL SECOND HARMONIC GENERATION IN POLYVINYLIDENE FL UORIDE FILMS J. G. Bergman, Jr., J. H. McFee, and G. R. Crane Bell Telephone Laboratories, Holmdel, New Jersey 07733 (Received 10 November 1970) Oriented films of polyvinylidene fluoride [(CH CF ).I. a polar polymer possessing symmetry 2 2 mm2, can be made significantly pyroelectric and optically nonlinear by poling in an electric field. A pyroelectric coefficient (dP/dT=2.4±0. 7 nC/cm 2o C) comparable to that of single- crystal LiNb03 is observed. The nonlinear optical coefficients d33 • d 32 • and d3 ! of polyvinyli- dene fluoride (PVF ) are measured relative to d of crystalline quartz [d (PVF )2d ! (PVF )