Effect of re-oxidation on dielectric properties in Ni-MLCC 教程.pdf

J Electroceram (2008) 21:22–28 DOI 10.1007/s10832-007-9072-z Effect of re-oxidation on dielectric properties in Ni-MLCC Hiroshi Kishi Youichi Mizuno Tomoya Hagiwara Hirokazu Orimo Hitoshi Ohsato Published online: 21 March 2007 # Springer Science + Business Media, LLC 2007 Abstract The effect of re-oxidation treatment on the Keywords Rare-earth . BaTiO3 . Dielectric properties . solubility of dopants and the dielectric properties of rare- Capacitors . Re-oxidation earths (La, Ho) and V-substituted BaTiO3 solid solutions, assuming the shell phase of X7R dielectrics, was investi- gated. Ho-V-substituted samples showed larger increase of 1 Introduction the lattice parameter and Tc by re-oxidation treatment compared with La-V-substituted samples. Electron spin In recent years, multilayer ceramic capacitors (MLCCs) resonance measurements revealed that the oxidation of V3+ with Ni internal electrodes composed of more than 800 to V4+ or V5+ appeared in the range in which the increase of dielectric layers of about 1 μm thickness have been mass- lattice parameter by re-oxidation treatment was observed. produced. To produce such thin-dielectric-layer MLCCs This suggests that the increase of Tc is due to the change of with highly reliable electrical characteristics, many studies preferential occupational site of Ho ion from A -site to B- have been done on the dielectric materials focusing on the site, being accompanied with the oxidation of V3+. We also degradation mechanism. [ 1] In nonreducible BaTiO3 (BT, investigated the effect of re-oxidation treatment on the AB O3) based dielectric materials used for Ni-MLCCs, it is electrical properties and microstructure in Ni-MLCC well known that the resistance degradation of di