SiO_2_TiO_2复合粉体制备条件对其光催化能力的影响研究.pdfVIP

39 2 Vol39 No2 2011 2 NEW CH EM ICAL MATERIALS 111 SiO2 / TiO2 1 2 1 孙秀果 吴国柱 王少辉 ( 1. 石家庄铁道大学材料科学与工程学院石家庄050043; 2. 沧州职业技术学院化学工程系 沧州0 1001) 用包覆沉淀法制备了纳米SiO / T iO 复合粉体, 考察了包覆速度温度对所得产品性能的影响, 通过 2 2 TEM 表征和紫外吸收光谱分析, 得出合适的包覆速度是改性的关键, 并初步探讨了其影响机理以紫外光照下降解甲基 橙为目标, 研究了改性温度和焙烧温度对纳米SiO / TiO 复合粉体的光催化能力的影响规律结果表明, 合适包覆速度 2 2 改性后的粉体粒度分布均匀, 紫外吸收能力增强, 分散性提高; 低温改性后的粉体, 低温煅烧后光活性较好, 高温改性后的 粉体, 高温煅烧后光活性较好 纳米二氧化钛, 二氧化硅, 表面包覆, 光催化 Study on ef fects of preparation conditions of SiO / nanoTiO composite 2 2 powder on the photocatalytic activi ty 1 2 1 Sun Xiuguo Wu Guozhu Wang Shaohui ( 1. College of M aterial Science and Engineering, Shijiazhuang Tiedao University, Shijiazhuang 050043; 2. Department of Chemical Engineering, Cangzhou Vocational College of T echnology, Cangzhou 0 1001) Abstract T itania nanoparticles coated w ith silica were prepared by the coat ing precipitation method. T he effect s of coating speed and t emperature on the properties of the products were studied by ultraviolet spectroscopy ( UV) and trans mission electron microscope ( TEM) . It w as found that t he appropriate coating speed was key factor. The corresponding mechanism was also proposed.The effects of coating temperature and calcination temp