Ce0.8Zr0.2O2+复合氧化物负载PdO+催化剂的NO-TPD研究.pdfVIP

G024 Ce0.8Zr0.2O2 复合氧化物负载PdO 催化剂的NO-TPD 研究 马 磊* 卢春山 李小年 （浙江工业大学化学与材料学院资源与环境催化研究所， 绿色化学合成技术国家重点实验室培育基地，杭州 310032 ） 摘 要 本文对PdO/Ce0.8Zr0.2O2 催化剂进行了NO-TPD 和 CO-TPR 研究。研究结果显示吸附的NO 在PdO/Ce Zr O 催化剂表面发生了解离，脱附产物除了NO 之外还有N 和N O 。Pd 的负载量极大 0.8 0.2 2 2 2 地影响催化剂的NO 吸附性能，晶相PdO 对吸附的NO 的解离作用要强于高分散的PdO ，晶相PdO 的量越多发生解离的NO 就越多，生成的N2 也越多。同时，晶相PdO 的存在会抑制N2O 在PdO 表 面的形成，从而降低脱附产物中N2O 的选择性，晶相PdO 的量越多这种作用越强烈。 关键词 PdOCe0.8Zr0.2O2 催化剂 NO-TPD 晶相PdO 中图分类号 文献标识码 文章编号 THE NO-TPD RESEARCH OF Ce Zr O MIXED 0.8 0.2 2 OXIDE SUPPORTED PALLADIUM CATALYSTS Lei MA*, Chunshan LU and Xiaonian LI （Resources Environment Catalysis Institute of Zhejiang University of Technology, State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Hangzhou 310032 ） Abstract In this paper, the Ce0.8Zr0.2O2 mixed oxide supported PdO catalysts have been investigated by the NO-TPD and CO-TPR. The experiments results exposes that the adsorbed NO were dissociated on the surface of PdO/Ce Zr O catalysts, and N and N O formed at the same 0.8 0.2 2 2 2 time. The property of adsorbing NO of the PdO/Ce0.8Zr0.2O2 catalysts is determined by the loadings of Pd. The function of dissociating the adsorbed NO on the Pd crystals is much higher than that on the dispersed Pd. This function enhances with the loading of Pd increasing. On the same time, the form of N2O is restrained by the Pd cryst