微波消解-浊点萃取-石墨炉原子吸收光谱法测定铜尾矿中痕量铜.docVIP

微波消解-浊点萃取-石墨炉原子吸收光谱法测定铜尾矿中痕量铜 张春梅，王小宽，杨兴华，杨欣( 本文档由【中文word文档库】提供，转载分发敬请保留信息； 中文word文档库免费提供海量教育、范文、学习、政策、报告和经济类word文档。 (怀化学院 化学与化学工程系，湖南 怀化 418008) 摘 要建立微波消解前处理、浊点萃取(CPE)预富集、石墨炉原子吸收光谱(GF-AAS)法测定铜尾矿中痕量铜的方法。铜尾矿经微波消解以后，和1-(2-吡啶偶氮)-2-萘酚(PAN)反应生成疏水性的络合物，被萃取到Triton X-100非离子表面活性剂胶束相中，用GF-AAS法测定胶束相中的。在优化的实验条件下，本方法的富集倍率为25倍，检出限为0.36 ng/mL，对浓度为2.0 ng/mL的样品溶液进行6次平行测定，相对标准偏差(RSD)为2.7%。该联用方法溶样时间短、试样溶解完全；不使用挥发性有机物质萃取、安全低毒结果准确可靠适用于铜尾矿中痕量的含量测定。 关键词：铜；微波消解；浊点萃取；石墨炉原子吸收光谱法 中图分类号：O657.32 文献标识码：A 文章编号： Determination of trace copper in copper tailing by microwave digestion-cloud point extraction-graphite furnace atomic absorption spectrometry ZHANG Chun-mei, WANG Xiao-kuan, YANG Xing-hua, YANG Xin﹡ (Department of Chemistry and Chemical Engineering, Huaihua College, Huaihua 418008, China) Abstract:A combination method for the determination of trace copper in copper tailing by microwave digestion-cloud point extraction(CPE)-graphite furnace atomic absorption spectrometry(GF-AAS) was established. Copper ion(Cu2+) reacted with 1-(2-pyridineazo)-2-naphthol(PAN) to form a hydrophobic complex after microwave digestion. The complex was extracted into Triton X-100 non-ionic surfactant micelle phase, and then the Cu2+ in the phase was determined by GF-AAS. Under the optimum conditions, the limit of detection was 0.36 ng/mL(3σ) for Cu2+ with the enhancement factor of 25 and relative standard deviation(RSD) of 2.7%(n=6, c=2.0 ng/mL). Compared with traditional acid solution method, the dissolving time of microwave digestion was short, and the sample dissolution was complete. It also showed the merits of lower toxicity, good reproducibility and low detection limit compared with other methods, which shows great promise for determination of trace Cu2+ in real copper tailing samples. Keywords:copper; microwave digestion; cloud point extraction; graphite furnace atomic absorption spectrometry 尾矿堆积导致严重的环境污染和资源浪费。铜是工业生产中重要金属元素，因此，测定尾矿中铜元素含量，在铜尾矿开发过程中日趋重要[1]。 目前，国内外文献报道测定痕量铜的方法主要有：光度法[2]、电化学传感法[3]、原子发射光