长支链聚乳酸的制备及结构与性能的研究论文.pdfVIP

长支链聚乳酸的制备及结构与性能的研究 尤金秀 俞炜 周持兴 上海交通大学 上海 200240 本文利用聚乳酸(PLA)与相同含量的三官能团单体季戊四醇三丙烯酸酯(PETA)，在 过氧化物含量为0.2％，0.3％，0.4％的条件下，熔融自由基反应分别制备长支链聚乳酸(简称 LCBPLA)P1，P2，P3。并对聚合物的结构和力学性能做了研究。 红外测试结果表明：产物在1631cm-1处出现一个小的吸收峰， （图1所示），这是C=C 双键的特征峰，来自于PETA分子上的C=C双键，说明PETA已经接枝到PLA主链上[1]。 PreparationofLongChainbranchespolylacticacidandtheeffectof itsstructureonproperties YOUJinxiuYUwe ZHOUchixing ShanghaiJiaoTongUniversity,Shanghai,2002401 Abstract:Thisarticlepresentsthepreparationoflongchainbranchespolylacticacid(LCBPLA)by melt radicals reaction with the pentaerythritol riacrylate triacrylate (PETA) and bis(1-methyl-1-phenylethyl)peroxide(DCP)(0.2％,0.3％,0.4％,wt％).FTIRspectroscopy indicatesthatanewbandappearsatabout1631cm-1forLCBPLAsampleattributedtothestretching vibrationoftheC=CinthePETAmolecule,whichmeansthatPETAreactedontothePLAchains successfully.Cole-ColeplotwasusedtodeterminelongrelaxationprocessofgraftedPLAsamples whichattributedtotheexistenceofLCB.ItwasfoundthatlinearPLAisclosetoasemicircle,while thecurvesofP1,P2andP3arehigherthanthatoftheneatPLA.HigherdegreeofLCBinproducts ledtolongerrelaxationwhichmeansthatP1,P2andP3havemuchlongerrelaxationtimewiththe moreLCB.AndthechangedstructureofproductseffectedthemechanicsperformanceofLCBPLA. ComparedwithneatPLA,tensilestrengthofP1,P2andP3increaseslightly,whiletheimpact strengthandbendingstrengthincreasedsignificantly,especiallytheimpactstrengthmostobvious. Themechanicalpropertiesofmaterialsimprovedmoreobviouslywiththeincreaseofthecontent ofLCB. Keywords:LCBPLA;Meltradicalsreaction;characterization; Mechanicsperformance