甲醇及合成气制二甲醚中不同粒径的HY分子筛及复合Cu_Mn_Zn_HY催化剂.pdfVIP

2010 Chinese Journal of Catalysis Vol. 31 No. 5 文章编号: 0253-9837(2010)05-0591-06 DOI: 10.3724/SP.J.1088.2010.91105 研究论文: 591~596 甲醇及合成气制二甲醚中不同粒径的 HY 分子筛及复合 Cu-Mn-Zn/HY 催化剂 于 翔, 王军华, 张立伟, 侯昭胤, 费金华, 郑小明 浙江大学化学系催化研究所, 浙江杭州310028 摘要：通过改变导向剂的老化时间, 制备了一系列不同粒径的 HY 分子筛作为脱水催化剂, 考察了甲醇脱水反应性能; 将其与铜 基甲醇合成活性组分 Cu-Zn-Mn 组成双功能催化剂, 考察了催化剂对合成气直接制二甲醚反应的催化性能. 结果表明, 粒径为 820 nm 的 HY 分子筛在甲醇脱水中表现出较高的催化活性; 以其作为脱水组分的双功能 Cu-Zn-Mn/HY 催化剂也表现出较高的 催化活性和良好的稳定性. 关键词：合成气; 二甲醚; 铜; 锰; 锌; HY 分子筛; 双功能催化剂; 甲醇脱水 中图分类号：O643 文献标识码：A Dimethyl Ether Synthesis from Methanol and Syngas over Different Sized HY Zeolite and Cu-Mn-Zn/HY Bifunctional Catalyst * YU Xiang, WANG Junhua, ZHANG Liwei, HOU Zhaoyin, FEI Jinhua , ZHENG Xiaoming Institute of Catalysis, Department of Chemistry, Zhejiang University, Hangzhou 310028, Zhejiang, China Abstract: A series of HY zeolites with different particle sizes were prepared using a hydrothermal route by varying the aging time of direct- ing agent. The HY samples were used for methanol dehydration to dimethyl ether (DME) and also used as a dehydration component in a hybrid Cu-Mn-Zn/HY catalyst for CO direct hydrogenation to DME. The 820 nm sized HY zeolite exhibited the highest methanol dehydra- tion activity. In the direct DME synthesis from syngas, the hybrid Cu-Zn-Mn/HY(820 nm) catalyst also had higher activity and stability at 4 800 h¯1, 2.1 MPa, and 253 oC. Key words: syngas; dimethyl ether; copper; manganese; zinc; HY zeolite; bifunctional catalyst; methanol dehydration