ZSM-5分子筛在低碳烷烃脱氢中催化应用.pdfVIP

第 20 卷 第 5 期 化 　学 　进 　展 Vol. 20 No. 5 2008 年 5 月 PROGRESS IN CHEMISTRY 　May , 2008 ZSM5 分子筛在低碳烷烃脱氢中的催化应用 胥月兵 　陆江银 　钟 　梅 　王吉德 (新疆大学 石油天然气精细化工教育部重点实验室 　乌鲁木齐 830046 ) 摘 　要 　ZSM5 分子筛是应用广泛的催化体系 ,常用于烷烃的芳构化 、催化裂化及异构化 。近年来因其 独特的孔道结构及表面酸碱特性 ,开始应用于低碳烷烃脱氢 。本文综述了 ZnZSM5 及 GaZSM5 催化剂对 低碳烷烃的脱氢理论研究 ,概述了 FeZSM5 、CrZSM5 、PtZSM5 以及一些其他过渡金属催化剂对低碳烷烃 的催化应用 ;探讨了 ZSM5 基催化剂的影响因素如硅铝比、焙烧温度及制备方法等 , 以利于对低碳烷烃脱氢 作进一步了解 ;最后对 ZSM5 催化体系进行了评述及展望 。 关键词 　ZSM5 分子筛 　脱氢 　低碳烷烃 　金属元素 ( ) 中图分类号 : O6433 ; TQ031. 4 　文献标识码 : A 　文章编号 : 1005281X 2008 Catalytic Application of ZSM5 Molecular Sieve for Light Alkanes Dehydrogenatoin Xu Yuebing 　Lu Jiangyin 　Zhong Mei 　Wang Jide ( Key Laboratory of Oil Gas Fine Chemicals , Ministry of Education , Xinjiang University , Urumqi 830046 , China) Abstract 　ZSM5 molecular sieve is widely used as catalyst for aromatization , catalytic cracking and isomerization. Recently the ZSM5 is applied to light alkane dehydrogenation due to its unique bore configuration and the character of surface acidity. This paper summarizes the progress of ZSM5 in application and theoretical research for light alkane dehydrogenation , including ZnZSM5 , GaZSM5 for dehydrogenation theory , and the ZSM5 catalysts modified with Fe , Cr , Pt and some other transition metals prepared by liquidion exchange and impregnation methods. The influencing factors of ZSM5 based catalysts such as SiAl , calcination temperature and the preparation methods are discussed. Future prospects o