铋磷钼蓝分光光度法测定硅硅中磷.docVIP

铋磷钼蓝分光光度法测定硅中磷摘要研究用抗坏血酸还原, 磷与钼酸铵、硝酸铋形成蓝色的显色反应。试验了酸度、显色时间的影响, 确定了最佳测定条件。加标回收率达97.88%,用此方法简单、快速且稳定，能获得满意的分析结果。 关键词磷; 硅铁;分光光度法; 铋磷钼 中图分类号: O657. 3　　　文献标识码: BDetermination of Phosphorus Content in ferro-silicon alloy by Molybdobismuthylphosphoric Blue Spectrophotometric Method ZHANG Jia- hui ( Testing Center，Panzhihua University，Panzhihua 617000， Sichuan) Abstract:This paper studied the color reactions of which the blue ternary complex of phosphorus, ammonium molybdate and bismuth nitrate was formed by the reducing of ascorbic acid，the influence factors such as the acidity, the coloration time, we