可控并流沉淀法制备草酸钴微细粉末的研究_黄凯.pdfVIP

30 2 矿 冶 工 程 Vo.l 30 l 2 2010 04 M INING ANDM TALLURG ICAL NGIN RING April2010 ¹ 1 2 2 黄 凯 , 郭学益 , 张多默 ( 1. , 100083; 2. , 410083) : , , , CoC O # 2H O, 330 e Co O , 2 4 2 3 4 930 e CoO : ; ; ; : TQ138. 12 : A : 0253- 6099( 2010) 02- 0059- 05 Study on PreparingCobaltOxalate FinePowder by Controlled ConcurrentFlow Precipitation 1 2 2 HUANG Kai, GUO Xue- i, ZHANG Duo-mo ( 1. School of M etallurg ical and Ecolog icalEng ineering, Beij ing University of Science and Technology, Beij ing 100083, China; 2. School of M etallurg icalScience and Engineering, Central South University, Changsha 410083, Hunan, China) Abstract: Rod-like, dendritic and flow er-like cobalt oxalate fine grains w ith homogenous grain size andw ell d ispersit w ere prepared b concurrent flow precipitation. The resu lts show ed that cobalt oxalate grains had 1-dmi ensional stretching grow th character, w h ile the reaction cond itions such as the concentration of the reactant, temperature, feeding rate, volume of underflow w ater, aging tmi e andw hether or not to be agitated, cannot change its grow th character and can on l had an effect on the particle size and dispersit of the products. Chem ical composition of the precipitate w as CoC O # 2H O b identification and anal zation, w hich can be thermall decomposed in the air at about 330 e and 2 4 2 Co O powder can be obtained, and CoO pow der can be obtained at about 930 e . 3 4 Key words: cobalt ox ide; cobalt