某硫化铜钼选厂尾矿回水利用的研究.docVIP

某硫化铜钼选厂尾矿回水利用研究 周 强，戈保梁，聂琪(1.昆明冶金研究院，云南 昆明650031；2.昆明理工大学，云南 昆明650093) 摘 要：某铜钼选厂采用磨矿-混合浮选-分离流程，经一粗一扫三精得到铜钼混合精矿，最后进行铜钼分离。该选厂的尾矿水碱度高，硫化钠含量高，如果直接返回利用会对铜矿物产生一定的抑制作用。尾矿回水试验表明，未经处理的尾矿回水和经阴离子絮凝剂或阳离子絮凝剂处理过的尾矿回水试验均得不到理想的试验结果。而采用KMG处理的尾矿回水进行试验，结果表明，回水对选 关键词：硫化铜钼矿；尾矿水；回水利用 中图分类号：X703 文献标识码：A 文章编号2010)03-0040-03 Utilization of Tailings Backwater from a Mineral Processing Plant of Copper-molybdenum Sulfide Ores ZHOU Qiang1, GE Bao-liang2, NIE Qi2 (1.Kunming Metallurgy Research Institute, Kunming 650031, Yunnan, China; 2.Kunming University of Science and Technology, Kunming 650093, Yunnan, China) Abstract: The recycling of the backwater in a Cu-Mo mineral processing plant was studied. In this plant, a flowsheet of grinding-bulk flotation-separation was adopted, and Cu-Mo bulk concentrate was obtained from a process containing one roughing, one scavenging and three stages of cleaning, and thereafter the Cu-Mo separation was conducted. Inasmuch the high alkalinity and high Na2S content, the direct feedback of the tailings backwater may cause a depression effect on copper minerals. Flotation tests show that it is hardly to obtain good results using the backwater without treatment or treated with anionic or cationic flocculants, while, using the backwater treated with KMG, good flotation index can be achieved. The results show that there is little impact on the technical index, and the backwater can be used circularly. Keywords: sulfide copper-molybdenum ore; waste water; utilization of backwater 我国95%的能源和85%的原材料来自矿产资。随着快速的人口膨胀和经济发展，对矿产资源。我国尾矿水的年排放36亿t，其中大部分没有经过任何处理，直接 某铜钼选厂采用磨矿混合浮选-分离选别流程，经 尾矿水净化是指对矿水中的有害物质进行物理、：① 尾矿水经过净化后回水再用，40%～70%。②尾矿库回水。尾矿排入 1 实验方法 该铜钼选矿厂最终尾矿水水质化验结果见表1。49.4，pH=13。 表1 尾矿水水质成分/(mg · L) Cu Mo S Fe As 0.0411 2.4761 538.43 0.0364 ＜0.01 本文采用全新水、未经处理尾矿回水、经处理后的1。图1 选矿试验流程2 试验结果 2.1全新水试验 按照图1所示流程，使用全新水进行浮选试验，结2。2 全新水试验结果Cu Mo Cu Mo 钼精矿 0.28 0.54 48.32 0.25 85.52 铜精矿 2.03 21.75 0.08 76.35 1.01 中矿1 0.03 1.89 26.53 0.10 5.0