某铅锌尾矿中锌矿物回收利用工艺的研究[J].docVIP

某铅锌尾矿中锌矿物的回收利用工艺研究 王淑红，孙永峰 (山东理工大学，山东 淄博255049) 摘 要：本文所用试样为贵州某铅锌矿老尾矿，由于存放时间比较长，矿石性质发生了较大的变化，III精矿精选三次、两次精矿合并作为最后精矿的闭39．75％、回收率73．74％的指标。 关键词：铅锌矿尾矿；锌氧化矿；浮选；羟肟酸 中图分类号：TD982 文献标识码：B 文章编号2009)12-0063-03 Study on the recovery of zinc minerals from the tailing of a lead zinc mineral processing plant WANG Shu-hong, SUN Yong-feng (Shandong University of Technology, Zibo 255049, China) Abstract: The sample used in the experiment came from a Lead Zinc mineral processing plant of Guizhou province. The tailing of the plant had placed in the open area for more than a decade, and the properties of the mineral had greatly changed, which made it very difficult to separate. The exploratory experiments indicated that the ZnS firstly collected, ZnO second principle flowsheet was very necessary to the mineral. Then the reagents used in both collections were determined: in first flotation, CuSO4 was used to activate sphalerite, then Aero Xantathate was used as collector; in second flotation, NaS was used as sulphurator, CuSO4 as activator, Aero Xantathate and Hydroximic acid as collectors. The flowsheet- one roughing, four scavenging, the rough concentrate and the concentrate of the third scavenging were both concentrated three times, the two concentrate mixed as the final concentrate was attained through a great deal of experiments. The concentrate got from the closed circuit contained 39.68% Zn with a recovery of 73.74%. Keywords: tailing of lead zinc mineral; oxidized zinc mineral; flotation; hydroximic acid 本文所用的试样来自贵州某铅锌选矿厂的尾t，由 由于尾矿存放时间较长，存放期间风吹日晒 1 试验研究 1．1矿样的物质组成分析 直接取矿样进行筛分试验，结果表明：矿样2mm的矿石约占11．26％。对筛上产品考查 化学分析结果表明，矿石中所含的有价金属11．42％和3．37％。脉石 锌尾矿中锌矿物的物相分析。对矿石中锌矿1。 从尾矿中锌矿物的物相分析结果来看：①锌59．28％的锌是以硫化锌的形式存在的，39．75％，但闪锌矿依然是锌尾矿中30．30％的锌是30．30％9．46％的锌是以硅酸锌的形式存在的，可能 总的看来，锌尾矿中只有闪锌矿相对好选一59．28％；剩下的40．72％的10．42％，因此，占总锌30．30％的氧化产物 1．2选矿方案和浮选药剂的选择 锌尾矿选矿方法的确定。对于尾矿中所含的30．30％4g／cm左右，而脉石中的2．7g／cm左右，可以 经过多次的摇床和螺旋溜槽试验表明：精矿20％左右，相对于原矿品位11．42％来 经过