硫酸处理对TiO_2薄膜光催化降解亚甲基兰溶液的影响.pdfVIP

第 30 卷 　第 6 期 电 子 器 件 Vol. 30 　No . 6 20 07 年 12 月 　　　 Ch inese J ou r nal Of Elect ro n D evices 　　 D ec . 20 07 Ef fect ion of H SO r eat men t on Phot oca talyt ic Act ivit y iO hin 2 4 2 3 Film on Gla ss f or Degra da t ion of Met hylene Blue YI N L i2son g , C H EN Yon g2pi n g , A N Mi n , F A N H ai2l u ( S ch ool of P hy sic s and ec hn olog y , Cent ur e S out h U niv er sit y , Ch an gsh a 4 10083 , Chin a) Abstr act : h e u niform t ra n sp ar ent iO2 n anomet er t hi n fil m w as p r ep ar ed w it h sol2gel met ho d at 400 ℃for 2 h . h e as2calcin ed i O2 na nomet er t hin fil m w as t r eat ed i n differ ent H2 SO4 aqueou s so lu tion for 2 4 h . Fi2 n all y , t he t reat ed i O2 t hi n film wa s again h eat2tr eat ed at 300 ℃400 ℃、50 0 ℃for 0 . 5h re sp ect ively . h e st ruct ur e of iO2 t hin fi lm befor e an d afte r t A S surf ace aci d t r eat men t w as cha racter ized by XRD 、A FM 、 UV2vi s. St udied t he effect of concent r ation o f H2 SO4 on p hoto degr adat ion of met h ylene bl ue , t he r esult s show t hat p hoto cat alyt ic act ivit y of t r eat ed iO2 t hi n fil m w as effectivel y en hanced . h e analy si s of XRD 、 ult r avio let ab sorp tion an d A FM show t hat t he p hot ocataly tic acti vi t y of iO2 t hi n fi lm dep end s st ron gly on t h e chan ge of su rface micro st r uct u r e an d size of p article . h e H2 SO4 op t imu m co ncen t rat io n i s 0 . 4 mol/ L Key wor ds : i O2 t hi n fil m ; sol2gel met ho d ; H2 SO4 ;p hoto cat al ytic acti vi ty E EAC