HPC_PAN共混温敏膜的溶胀动力学研究.pdfVIP

HPC/ PA N / # 35 # HPC/ PAN * 1 2 3 , , ( 1 , 710021; 2 , 710048; 3 , 710021) 采用羟丙基纤维素( Hydroxypropylcellulose, HPC) 和聚丙烯腈( PAN) 为原料制备了系列共混温敏膜; 研究了原料配比pH 值以 温度对共混膜溶胀速率的影响结果表明, 当温度在最低临界溶解温度( LCS ) 以下且 pH = 1.4 时, HPC/ PAN 共混膜的溶胀速率随着体系中HPC 用量的增加而加快, 高分子链的松弛过程成为膜溶胀的 主要控制因素;在 pH = 7.4 的弱碱性条件下, 水分子的扩散渗透成为膜溶胀过程的主要控制因素温度对溶胀速率 的影响与pH 值有关,pH 值对膜溶胀速率的影响与温度有关 : O636. 1 :A Studies on Sw elling Kinetics for HPC/ PAN Thermo-sensitive Blending Films 1 2 3 GONG Guoli , LI Xiaoyan , LI Hui ( 1 College of Life Science and Engineering, Shaanxi University of Science and echnology, Xi. an 710021; 2 Apparel and Art Design College, Xi. an Polytechnic U niversity, Xi. an 710048; 3 College of Resource and Environment, Shaanxi University of Science and echnology, Xi. an 710021) Abstract Series of thermo-sensitive blending films are prepared from hydroxypropylcellulose and polyarcyloni- trile. he effects of materials ratio, pH value and temperature on t hese blending films swelling velocity are investiga- ted. As temperature is low er than LCS , different results are found blending films samples are dipped in acid or base condition, such as pH value being 1.4 and 7.4 respectively. Results from pH value of 1.4 show that sw elling velocity of HPC/ PAN blending films increases wit h the addition of HPC, filmcs swelling is mainly controlled by polymer chain relaxat ion. But, it is controlled by w at er molecules diffusion under pH value of 7. 4. Sw elling velocity is