丙酸_乙酸对低能耗生物除磷脱氮系统影响.pdfVIP

中国环境科学 2008,28(8) ：673~678 China Environmental Science 丙酸/乙酸对低能耗生物除磷脱氮系统的影响 * 李洪静,陈银广,顾国维 ( 同济大学环境科学与工程学院,污染控制与资源化研究国家重点实验室,上海 200092) 摘要：以厌氧-低氧(0.15~0.45mg/L)条件下的序批式反应器(SBR)为研究对象,探讨了丙酸/ 乙酸比例对低能耗同时生物除磷脱氮系统的影响. 结果表明, 以丙酸/ 乙酸比为 1/1(SBR-A)或 2/1(碳摩尔比)为碳源(SBR-B),系统中均发生同时生物氮和磷的去除,低氧阶段氨氮被全部氧化, 并且没有亚硝酸盐的大量累积.与 SBR-A 相比,SBR-B 中厌氧阶段磷释放量少,聚羟基戊酸(PHV)和二甲基三羟基戊酸(PH2MV)合成量高, 低氧末磷剩余量少,硝态氮累积少,SBR-B 中总氮和磷的去除率(分别为82%和97%) 比SBR-A(分别为68%和94%)高.因此,丙酸/ 乙酸比例 的增加有助于提高同时生物除磷脱氮系统中氮和磷的去除效果. 关键词：序批式反应器；丙酸/ 乙酸；低能耗；同时生物除磷脱氮 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2008)08-0673-06 Effect of propionic to acetic acid ratio on biological nitrogen and phosphorus removal with low energy * consumption. LI Hong-jing, CHEN Yin-guang , GU Guo-wei (State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China). China Environmental Science, 2008,28(8)：673~678 Abstract ：Two sequencing batch reactors, SBR-A and SBR-B with propionic/acetic acid carbon molar ratio of 1/1 and 2/1, respectively, Which were operated under conditions of anaerobic-low dissolved oxygen (DO) (0.15~0.45mg/L), and the influences of propionic to acetic acid ratio on biological nitrogen and phosphorus removal were investigated. The results showed that the simultaneous biological nitrogen and phosphorus removal occurred in both SBR-A and SBR-B, and the ammonia was completely oxidized during the low DO period without substantive nitrite accumulation. Compared with SBR-A, SBR-B showed less anaerobic phosphorus release and more anaerobic polyhydroxyvalerate (PHV) and polyhydroxy-2-methylvalerate (PH2MV) syntheses, but had lower phosphorus and nitrate concentrations at the end of low DO stage. The total nitrogen and phosphorus removal efficiencies were higher in SBR-B (82% and 97%, r