模板诱导均相沉淀法对HAP形貌控制及机理的研究.pdfVIP

Material Sciences 材料科学, 2012, 2, 149-155 doi:10.4236/ms.2012.24027 Published Online October 2012 (/journal/ms.html) Morphology Control and Mechanism of Hydroxyapatite Synthesized by a Template-Mediated Homogenous * Precipitation Route # Ya’nan Chen, Zhiliang Huang , Xing Tian, Li Chen, Hanqi Wu, Ru’an Chi School of Material Science and Engineering, Wuhan Institute of Technology, Wuhan Email: #hzl6455@126.com Received: Jul. 29th th st , 2012; revised: Aug. 14 , 2012; accepted: Sept. 1 , 2012 Abstract: Different morphologies hydroxyapatites (HAPs) were synthesized in a controllable way by a template- mediated homogeneous precipitation route. The morphologies and compositions of synthesized HAPs were charact- erized by SEM and XRD, and the surface tensions of different reaction solutions were tested. The template-mediated mechanism for the morphology control according to the crystal growth theory was explained. The results suggested that with the changes of template agent types and the concentrations of reaction solution, the surface energy γlg of precursor liquid can be changed. Then the interface energy γsl of the nucleation at the different crystal plane could be affected. The morphologies of synthesized HAPs were controlled by the precursor liquid surface tension γlg and the crystal interface energy γ . When γ was controlled under 28 mN/m, the morphology of HAP was controlled to become nanoflower. sl lg When γlg was controlled between 28 mN/m and 48 mN/m, the HAPs had the mixed