基于硅材料分子印迹聚合物制备及应用.pdfVIP

22 1 化 学 进 展 Vo.l 22 N o. 1 2010 1 PROGRESS IN CHEM ISTRY Jan. , 2010 * 基于硅材料的分子印迹聚合物的制备及应用 阚显文 尹宇新 耿志荣 王志林* * (南京大学化学化工学院配位化学国家重点实验室 南京 210093) 分子印迹 合物因制备简单稳定性好且具有分子识别功能使其在色谱分离固相萃取化学 传感模拟酶催化等方面有了广泛的应用近年来, 基于硅材料的分子印迹 合物发展较为快速本文主要 介绍了硅材料的分子印迹 合物的制备及分子识别性质研究, 并对其应用进行了分类, 在此基础上对其将来 的发展进行了展望 分子印迹 合物 硅材料 分子识别 : O632. 12; O6 2. 6 : A : 100 281X( 2010) The Preparation and Applications ofM olecularly Imprinted Polym ers Based on SilicaM aterials * * K an X ianw en Yin Yux in G eng Zh irong Wang Zh ilin ( StateK ey Laboratory of Coord ination Chem istry, School of Chem istry and Chem icalEngineering, Nanjing Un iversity, Nanjing 210093, Ch ina) Abstract Ow ing to the advantages of easy preparation, stability andmolecu lar recognition capacity, molecu larly mi printed polymers (M IPs) have been applied in chromatography separation, solidphase extraction, m mi ic enzym e catalysis, electrochem ical sensor, and other fields. In recent years, M IPs based on silica materials have been developed rap idly. H ere, the preparation, adsorption and recognition properties studies ofM IPs based on sili con m aterials using as matrix and substrate materials are introduced, and the applications ofM IPs based on silica materials are review ed. The prospects for the future development ofM IPs based on silica materials is also given. K ey words molecularly mi printed polym ers (M IPs); silica