PBT树脂合成中催化剂性能研究.docxVIP

宝瑞（国际）塑胶PPBT树脂合成中催化剂性能的研究刘瑶，张纪梅，臧国强，魏君(1．天津工业大学，天津300160；2．中国石油化工股份有限公司天津分公司研究院，天津300271)摘要：以对苯二甲酸(PTA)和1，4-T-醇(BD)为原料，采用直接酯化法合成聚对苯二甲酸丁二醇酯(PBT)；比较了钛酸四异丙酯(唧)、钛酸四丁酯(TBT)以及自制的复合催化剂(，rY)3种催化剂的催化活性；讨论了催化剂类型及其用量对酯化速率、酯化率、四氢呋哺(THF)生成量、聚合反应速率和PBT物理性能的影响。结果表明：在催化剂加入量(相对于PTA催化剂的Tj含量)为200—600 v．g／g时，TY， I朔’和TBT催化剂的酯化率均能达到90％，TY催化剂较 rPr和TBT能有效地提高酯化反应和聚合反应的速率，并能减少THF的生成量；采用TY催化剂，酯化率达95％，THF生成量降低20％ -40％，聚合速度提高30％一50％，得到的PBT特性黏数达到0．880 dL／g，产品色相L值最高为79．19，b值最低为O．23；TY催化剂的催化活性较TBT和11PT高，而TBT催化剂稍优于TPT催化剂。关键词：聚对苯二甲酸丁二醇酯直接酯化法钛系催化剂复合催化剂催化活性中图分类号：TQ323．4 文献标识码：A 文章编号：1001．0041(2013)03-0016-03Performance of catalysts for PBT synthesisLiu Yao ，Zhang Jimei ，Zang Guoqiang ，Wei Jun。(1．Tianjin Polytechnic University，Tianjin 300160；2．Research Institute ofSINOPEC Tianjin Company，Tianjin 300271)Abstract：Polybutylene terephthalate(PBT)was synthesized from terephthalic acid(P，rA)and 1，4-butanediol(BD)via di．rect esterfication．The catalytic activity of tetraisopropyl(TP，r)，tetrabutyl titanate(TBT)and self-made composite catalyst (TY)was compared．The efects of catalyst variety and amount on the esterification reaction rate，esterification conversion rate，tetrahydrofuran (THF)yield，polymerization reaction rate and physical properties of PBT were discussed．The results showed that TY ， and TBT all provided the esterification conversion rate up to 90％．and TY can increase the reaction rates of esterifica．tion and polymerization and decrease the THF yield more efficiently when the catalyst addition was 200—6OO g／g(Ti content based on PTA)；TY provided the esterification conversion rate up to 95％，THF yield with a decrease of20％一40％，polymeri．zation reaction rate with an increase of 30％一50％ and the resulting product had the intrinsic viscosity of 0．880 dL／g and the maximum L value of 79．19 an d the minimum b value of 0．23；TY had the highest catalytic activity among these three catalysts and TBT was slishfly better than TP，r．Key words ：polybutylene terephthalate；direct esterification；titanium catalyst；composit