量子尺寸纳米TiO_2的水热制备及光催化性能.pdfVIP

第39 卷第3 期 浙 江 大 学 学 报( ) Vol. 39 No. 3 2005 年3月 Journal of Zhejiang University(Engineering Science) Mar. 2005 TiO 2 蒋玉龙, 王智宇, 唐培松, 钱国栋, 樊先平 (浙江大学 硅材料国家重点实验室, 材料科学与工程学系, 浙江 杭州 310027) : 在钛酸丁酯和乙醇体系下, 利用水热法制备了平均粒径为 4~ 10 nm 量子尺寸锐钛矿型纳米二氧化钛粉 末, 并研究了此粉末 光催化活性和晶粒粒径、荧光发射光谱 关系. 结果表明: 制备 纳米二氧化钛粉末在粒径为 8~ 9 nm 时光催化活性最好, 当晶粒粒径再减小以后, 由于表面活性 增加导致晶粒表面羟基 增加, 成为电子和空 穴 复合中心而使活性降低. 同时此粉末 荧光发射光谱中并没有发现荧光峰位随着晶粒粒径变小而发生位移, 并 且荧光发射光谱峰 强度和光催化活性之间没有成比例 关系. : 二氧化钛; 水热法; 量子尺寸效应; 光催化 : T Q134 : A : 1008 973X(2005) 03 440 05 Hydrothermal preparation and photocatalytic properties of quantum size TiO2 nanoparticles JIANG Yu long, WANG Zhi yu, T ANG Pei song, QIAN Guo dong, FAN Xian ping ( State K ey L abor atory of Silicon Materials , Dep ar tment of M ater ials Science and Eng ineer ing , Zhej iang Univers ity , H ang hou 310027, China) Abstract: Anatase TiO2 nanoparticles were prepared by hydreothermal synthesis method with titanium n butoxide and ethanol as initial reagents. T he average grain size of the anatase TiO2 nanoparticles varied from 4~ 10 nm. Study of the dependence of photocatalytic property on the nanoparticle size and fluores cence spectrascopy show that the photocatalytic activities of the T iO2 nanoparticles with average grain sizes of 8~ 9 nm are better than those of other sizes. With the surface activity of nanosized titanium dioxide in creasing, the hydroxyl groups increase in grain surfaces. T he obtained surface hydroxyl groups are abun dant to facilitate the recombination of electron and hole and led to the decreasing photocatalytic activity of the nanoparticles. T