混合控制下腐蚀过程电化学动力学参数测定.pdfVIP

物理化学学报(Wuli Huaxue Xuebao) October Acta Phys. Chim. Sin., 2006, 22(10) ：1281耀1286 1281 [Note] 混合控制下腐蚀过程的电化学动力学参数测定 永韬1, 郭兴蓬2 (1 洋腐蚀与防护国防科技重点实验室, 中国船舶重工集团公司第七二五研究所, 山东青岛 266071; 2 华中科技大学化学系, 武汉 430074) 摘要 通过恒电量脉冲技术测定Q235 碳钢在天然海水中腐蚀过程的电化学动力学参数. 分别利用不同极化幅 度的恒电量瞬态响应分析获得极化电阻和Tafel 斜率, 进而计算腐蚀电流icorr. 并对比了恒电量方法和考虑扩散 影响的稳态极化曲线方法的测量结果. 结果表明, 采用恒电量强极化积分算法(CPSI)获得的Tafel 斜率与极化曲 线方法有很好的相关性. 同时, CPSI 测定的阴极Tafel 斜率符合氧还原反应的理论Tafel 斜率值. 因此, 采用恒电 量瞬态响应测量大大减小了浓差极化的影响, 有利于快速测定电荷传递和扩散传质混合控制下腐蚀过程的电化 学动力学参数. 关键词： 恒电量, Tafel 斜率, 混合控制, 碳钢, 腐蚀 中图分类号： O646, TG174. 42 Determination of Electrochemical Kinetic Parameters in a Mixture Controlled Corrosion System ZHAO, Yong Tao1, GUO, Xing Peng2 1 ( State Key Laboratory f or Marine Corrosion and Protection, Luoyang Ship Material Research Institute, Qingdao 266071, P. R. China; 2Department of Chemistry, Huazhong University of Science and Technology, Wuhan 430074, P. R. China) Abstract A transient analysis method, based on the coulostatic impulse technique, is developed. This method can compute the polarization resistance and Tafel slopes by analyzing the coulostatically induced transients with different amplitude over potential decay and, on the ground of their knowledge, evaluate the corrosion current, icorr. The experimental application concerns the behavior of carbon steel in natural seawater. Experimental results for carbon steel exposed to natural seawater show good agreement between the proposed method an