Electrodeposition and Surface Characterization of Sulfur on Polycrystalline Platinum from Sulfide Polluted Brine.pdfVIP

Electrodeposition and Surface Characterization of Sulfur on Polycrystalline Platinum from Sulfide Polluted Brine.pdf

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Electrodeposition and Surface Characterization of Sulfur on Polycrystalline Platinum from Sulfide Polluted Brine.pdf

Feb.2010,Volume4,No.2(SerialNo.27) JournalofChemistryandChemicalEngineering,ISSN 1934—7375,USA 麓Il*l舞;l {隧 ElectrodepoSitionandSurfaceCharacterizationofSulfur onPolycrystallinePlatinum from SulfidePollutedBrine FaizaMohamedAlKharafi,AimanYehiaSaad,BadrGhazyAteyaandlbrahim M ohamedGhayad ChemistryDepartment,FaculytofScience,KuwaitUniversity,Kuwait,Safat13060,Kuwait Received:December16,2009/Accepted:December24,2009 /Published:February28.2010 Abstract:Thispaperinvestigatedtheelectrodepositionofsulfuronpolycrystallineplatinum from sulfidepollutedbrine.Anodic Dolarizatioffpotentiostaticandelectrochemicalimpedancespectroscopy (EIS)techniqueswereperformed.TheslopeofWarburg straightlineinNyquiestplotoftheEISspectraperformedat0.0V indicatesdiffusioncontrolmechanism oftheelectrodeposition process.At0.5VtheR (determinedfrom EISmeasurements)increasedrapidlywithtimeindicatingmoresulfurdepositionandmore Dassivationofplatinumsurface.Samplessubjectedtopotentiostaticexperimentsat0.4,0.9and1.0VwereinvestigatedunderScanning ElectronMicroscope(SEM).SEM imagesrevealthedepositionofsulfuronthesamplesurfaces.Thedegreeofsulfurdepositcoverage anditsmorphologydependOllboththepotentialandtimeofdeposition. Keywords:Electr(】depositiOn,sulfurplatinum sulfidepollution 1.IntroductiOn Manymethodsoftreatmentarebeingusedofrthe removalofsulfideionsfrom pollutedwaters,including Dissolvedsulfideswhich.mostlyintheform ofHS。 biologicaltreatment[13],adsorption [141,oxidation ions,heavilycontaminatetheformationwatersofsour 【15,16].Among these methodselectrochemical oilandgaswellsandduringthedrillingofwellsofrthe oxidationofsulfidecontami

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