环氧化合物开环聚合催化剂研究进展.pdfVIP

29 2 Vol29 No . 2 2008 4 J o ur nal of Chem ical I nd us try E ng ineer ing Apr., 2008 1 1 2 2 陈 华 , 朱新宝 , 王康芳, 郝静琳 ( 1 , 210037; 2 , 22 803) : , , : ; ; : T Q426 : A :2008) Research progress on ringopening polymerization catalyst of epoxide Chen H ua 1, Zh u X inbao 1, Wang K angf ang 2 , H ao J ing lin2 ( 1Department of Chemistry, Nanjing Forestry University, Nanjing 210037, China; 2Yangzhou Chenhua Technology Group, Baoying 22 803, China) Abstract: The catalyst and mechanism of epoxide ringopening polymerization is introduced.T he application and t heir ad vantages and disadvantages of the cationic, the anionic, and the coordination ringopening polymerization method are discussed. The process progress of a variet y of catalyt ic system is introduced.T he enzyme and phosphorus nitriles catalyst w ith good pros pects for research are pointed out . Key words: Epoxide; Ringopening polymerizat ion; Catalyst , EO( PO) , ( EO) Possion Florry[ 4] Lew is ( PO) ( ECH) ( T HF) , , , [ 2] , 4~ 8 , , 2 6 ( PEG) , 10 ~ 10 1 ; , , [ 1] , : ( 1) , HBF4 , HClO4 , CF3 COOH, CF3 SO3 H; ( 2) Lew is [ 2, 3] BASFDuPont Great Lake , BF3 , SnC14 , A 1C13 , SbC1 , Et3 OBF4 , [ ]