《稀土化学导论》.pdf

分 析 化 学 第42卷 1182 Residue and Degradation of Cyantraniliprole and Its Main Metabolite in Pepper and Soil * HE Hong-Mei ,ZHANG Chun-Rong,ZHU Ya-Hong,ZHANG Chang-Peng,PING Li-Feng, ZHAO Hua,WU Min,TANGTao,CAI Xiao-Ming,LI Zhen (State Key LabBreeding Basefor Zhejiang Sustainable Plant Pest Control,Ministry of Agriculture Key Labfor Pesticide Residue Detection,Institute of Quality and StandardforAgro-products, ZhejiangAcademy of Agricultural Sciences,Hangzhou310021,China) Abstract An analytical method based on ultra performance liquid chromatography-tandem mass spectrometry was developed for the determination of cyantraniliprole and its main metabolite J9Z38 residues in pepper and soil. The fateof cyantraniliproleandJ9Z38 inpepper and soilwasalso evaluated. Thetarget compoundswere extracted with acetonitrile,cleaned up by C cartridge,and further analyzed by gradient ultra performance 18 liquid chromatography-tandem massspectrometry with electrospray ionization inpositive mode (ESI﹢)using a UPLC BEH C Column. The methodwasvalidated using fortified pepper and soil. Intra-day mean recoveries 18 of cyantraniliprole and J9Z38 at three spiked levels (0.01,0.10 and 1.00 mg/ kg) ranged from 88.6% to 105.7% withrelativestandarddeviationsof3.8%-15.1%. Inter-day meanrecoveriesof cyantraniliproleand J9Z38 were found between91.4% and 105.3% with relative standard deviations of 4.9%-12.3% at three spiked levels. Limits of quantification (LOQs) of cyantraniliprole and J9Z38 were 0.1and0.2 μg/ kg, respectively. Linear calibration functions with correlation coefficients of r0.9992 were obtained in the concentration range of 2.0-1