Al_SBA_15吸附脱除油品中_省略_Al_SBA_15zeolite_徐晓宇.pdfVIP

网络出版时间：2014-01-10 10:55 网络出版地址：/kcms/detail/51.1210.TE1055.001.html 石油与天然气化工 Al-SBA-15吸附脱除油品中碱性氮化物的研究 徐晓宇 沈 健 （辽宁石油化工大学化学化工与环境学部） 摘要：对硅铝比为 50 的 Al-SBA-15 介孔分子筛开展吸附脱除喹啉的十二烷溶液中碱性 氮化物的实验，研究其吸附脱氮工艺条件及性能。结果表明，碱性氮化物在 Al-SBA-15(50) 上的最佳吸附温度为 140 ℃，适宜的剂油质量比是 1 ∶30 ，适宜的吸附时间为 20 min 。此 时吸附量为 30.6 mg/g ，脱氮率为 68.02% ，吸附动力学可用准二级动力学方程表示。 关键词：介孔分子筛 吸附 脱氮 中图分类号：TE624.5+4 文献标志码：A Study on adsorpting basic nitrogen compounds from oil with Al-SBA-15 zeolite Xu Xiaoyu, Shen Jian (College of Chemistry，Chemical Engineering and Environmental Engineering, Liaoning ShiHua University, Fushun 113001， Liaoning， China) Abstract: The denitrogenation technological conditions and adsorbability of the Al-SBA-15 （50 ） mesoporous zeolite adsorb removal of basic nitrogen compounds from quinoline in dodecane solution was studied. The results show that the optimum temperature of basic nitrogen compounds adsorbs on the Al-SBA-15 （50 ） is 140 ℃, the suitable mass ratio of adsorbent/oil is 1 ∶30, the suitable adsorption time is 20 minutes, and the capacity of adsorption is 30.6 mg/g, the rate of denitrogenation is 68.02%. The adsorption dynamics in good agreement with the pseudo-second rate equation expression. Keywords: mesoporous zeolite; adsorption, denitrogenation 近年来，世界原油重质化和劣质化日趋严重。在全球剩余的可开采石油能源中，重油资 源达70%，重油能源在我国石油资源总储量中达到20%[1-2] 。这些重质油具有馏分重、碱性