二氧化钛纳米材料的合成及在水中降解的应用.doc

二氧化钛纳米材料的合成及在水中降解的应用 林晓亮 摘 要  Abstract Although TiO2 pHotocatalytic material has a low efficient utilization of solar energy ，the preparation of pHotocatalyst with high pHotocatalytic activity ，the immobilization of powder pHotocatalyst. In this paper，TiO2 powder was prepared by sol-gel method firstly，and the preparation conditions werer optimized by the orthogonal experiments.The main factors which affected the gelation process and catalytic capability were discussed.Then TiO2 powder was prepared by sol-gel method too.The amount of reagents including anhydrous ethanol ，distilled water，hydrochloric acid， and calcination temperature were were optimized，and the optimum preparation conditions were obtained. Through process optimization， prepared with good adsorption properties and pHotocatalytic properties of TiO2. Studies show that when tetrabutyl titanate， ethanol， deionized water and the amount of hydrochloric acid are 10mL， 40mL， 4mL， 8 drops， TiO2 adsorption and pHotocatalytic properties of the best. And prepared a series of different proportions of cerium-doped TiO2， under ultraviolet light to do on the degradation of methylene blue reaction， under the best conditions in the laboratory to determine the optimal doping. The experiments show that cerium-doped Ce-doped amount TO2 catalytic properties of light is much better than pure TiO2. Key words pHotocatalysis； TiO2； sol-gel method； S- doping degradation； 目 录 第一章 绪论 1 1.1前言 1 1.2有机小分子凝胶的形成机理 1 1.3凝胶的制备 2 1.4.1纳米二氧化钛光催化剂制备方法研究进展 2 1.4.2 TiO2 的掺杂改性 7 1.4.3 TiO2的实际应用及前景 8 1.4.4本课题的目的与研究内容 9 第二章 二氧化钛的合成及掺杂硫的合成 10 2.1 实验药品与仪器 10 2.1.1 实验试剂 10 2.1.2 实验仪器 10 2.2溶胶-凝胶的形成原理 11 2.3合成线路 11 2.4光催化剂的制备 11 2.5光催化剂活性测试 12 2.6影响成胶的因素 12 2.6.1温度对溶胶速率的影响 12 2.6.2冰乙醇加入量对凝胶速率的影响 13 2.6.3乙酸加入量对凝胶速率的影响 14 2.6.4浓盐酸滴加量对凝胶速率的影响 14 2.6.5去离子水对凝胶速率的影响 15 2.7结构表征 16 2.7.1 XRD分析 16 2.7.2比表面积的测定 17 2.8结果与讨论 19 2.8.1煅烧温度对凝胶的催化活性的影响 19 2.8.2 pH 对催化活性的影响 20 2.8.3催化剂加入量对催化活性的影响 21 2.9本章小结 22 第三章 非金属掺杂光催化剂的制备及催化性能的研究 23 3.1实验药品与仪器 23 实验仪