P204与N235协同萃取钕的研究.docVIP

P204与N235协同萃取钕的研究 常宏涛1,2，季尚军1,2，李梅1,2，柳召刚1,2，张称心1,2 （1.内蒙古科技大学 材料与冶金学院，内蒙古包头 014010 2.内蒙古科技大学 内蒙古自治区稀土现代冶金新技术与应用重点验室，内蒙古包头 014010） 摘要：采用非皂化的酸性萃取剂P204和碱性萃取剂N235协同萃取钕。研究了P204与N235的配比、萃取剂浓度、水相酸度、稀土浓度对P204与N235协同萃取钕的影响。结果表明，当N235与P204以体积比64、协同萃取剂与煤油的体积比11、pH为3.0时协同萃取钕的效果最好，随着稀土料液浓度的大，萃取量先增大后趋于平，并且最大饱和容量达28 gL(REO)，大于P204单独萃取钕的饱和容量。 关键词：P204；N235；协同萃取；钕 T845+.6 文献标志码：A 文章编号：1007-7545（2015）03-0000-00 Study on Synergistic Extraction of Neodymium by Mixtures of P204 and N235 CHANG Hong-tao1,2, JI Shang-jun1,2, LI Mei1,2, LIU Zhao-gang1,2, ZHANG Cheng-xin1,2 (1. School of Materials Science and Engineering Inner Mongolia University of Science and Technology, Baotou 014010, Inner Mongolia, China; 2. Inner Mongolia Autonomous Universities, Key Laboratory of New Technologies of Modern Metallurgy and Application of Rare Earth Materials, Baotou 014010, Inner Mongolia, China.) Abstract：eodymium was synergistic extracted by unsaponifiable acidic extractant P204 and alkaline extraction N235. The effects of ratio of P204 and N235, extractant concentration, aqueous phase acidity, and rare earth concentration on synergistic extraction of neodymium were investigated. The results show that the optimum synergistic extraction is obtained under the conditions including volume ratio of N235 and P204 of 6︰4, volume ratio of synergistic extractant and kerosene of 1︰1, and pH value of 3.0. Extraction capacity first rises and then tend to maintain with increase of concentration of rare earth feed liquid. The maximum saturation capacity of neodymium is 28 g/L (REO) which is higher than that of individual extraction of P204. Key words: P204; N235; synergistic extraction; neodymium 稀土是17种元素的总称，因其中的一种或几种元素作为添加剂使用，使得稀土元素的分离非常重要[12]。工业中常采用酸性萃取剂P204或P507萃取分离稀土元素，由于水相中的氢离子浓度对酸性萃取剂在萃取分离稀土元素的性能方面会产生较大的影响[34]，因此为了减小水相中氢离子浓度对萃取分离稀土元素的影响，目前工业中常采用无机碱皂化处理酸性萃取剂。采用皂化后的酸性萃取剂萃取分离稀土元素的方法能使水相酸度保持稳定，但使用无机碱皂化处理酸性萃取剂会给环境带来一定的污染。如采用氨水皂化处理会使得排放废水中氨氮排放量严重超标若采用氢氧化钠皂化，所得废水中钠盐含量较高，排放废水容易使土地盐碱化现象加剧，对植被破坏程度较大[56]。为了解决萃取剂皂化所造成