Solutions to Exercises-Chapter 7-沉淀与溶解平衡.docVIP

Solutions to Excercises Chapter 7 沉淀与溶解平衡 Ⅰ. ?Fill in the blanks 1. The Ksp expression for Ca3(PO4)2 is . If Qsp Ksp, ; if Qsp Ksp, . （Ksp(Ca3(PO4)2 ) = [Ca2+]3[PO43- ]2; the solution remains unsaturated; precipitation should occur） 2. The solubility of BaSO4 will if it is placed in 0.10 mol·L-1 BaCl2. This influence is known as . The solubility of BaSO4 will if it is placed in 0.10 mol·L-1 NaCl instead of 0.10 mol·L-1 BaCl2. This influence is known as .( be reduced; common-ion effect; be increased; salt effect) Ⅱ. Multiple Choice (only one is correct) (d)1.The solubility of saturated BaS solution (which contains a large amount of solid BaS) remains the same when which of the following substances is added? (a) Na2S (b) KCl (c) BaCl2 (d) H2O (a)2.The maximum concentration of Ba2+ that can exist in a solution in which the sulfate ion concentration is 5.5 × 10-4 mol·L-1 is (Ksp(BaSO4) = 1.08×10-10) (a) 2.0×10-7 mol·L-1 (b) 5.5×10-4 mol·L-1 (c) 2.0×10-5 mol·L-1 (d) 6.0×10-14 mol·L-1 (d)3. The relationship between the Ksp of AgBr and the molar solubility, S of AgBr in 0.20 mol·L-1 KBr is that Ksp equals (a) S 2 (b) S /0.20 (c) 4s3 (d) 0.20 S (b)4. How many moles of SrF2 will dissolve in I L of 0.10 mol·L-1 NaF, if Ksp (SrF2) = 7.9×10-10? (a) 2.8 ×10-5 (b) 7.9 ×10-8 (c) 7.9 ×10-9 (d) 4.0×10-9 (d)5. At the temperature at which the molar solubility of PbBr2 in water is 2.3×10-2 mol·L-1. What is the Ksp of PbBr2? (a) 5.3 ×10-4 (b) 1.2 ×10-5 (c) 2.4 ×10-5 (d) 4.9×10-5 (d)6.?The Ksp for Fe(IO3)3 (s) is 1×10-14. Consider what would happen if the following two solutions are mixed together. One solution contains Fe3+ and the other contains IO3 - at 25℃. At the instant of mixing, [Fe3+]= 1×10-4 mol·L-1 and [IO3-]= 1×10-5 mol·L-1. Which