Pt负载型二氧化钛纳米管纳米晶复合光催化剂的制备及其光.docVIP

Pt负载型二氧化钛纳米管纳米晶复合光催化剂的制备及其光 1 1 2 1 1 余威威 , 张青红 , 石国英 , 李耀刚 , 王宏志 东华大学 1. 纤维改性国家重点实验室; 2. 化学工程与生物工程学院, 上海 201620 摘 要: 结合强吸附能力与高光催化活性的催化剂有望更有效地除去废水中的污染物. 以 Degussa P25 二氧化钛为 原料, 采用水热法制备了二氧化钛纳米管简称为 TNTs, 将 TNTs 加入到溶有氯铂酸和柠檬酸还原剂的无水乙醇 中, 在蒸汽相水解装置中通过一步法制备了 Pt 负载型二氧化钛纳米管/纳米晶复合光催化剂. 蒸汽相处理过程中, 部分纳米管转变为锐钛矿相 TiO , 仍有部分以管的形式存在, 使纳米复合物保留了较高的吸附能力. 利用 X 射线 2 衍射XRD、透射电子显微镜TEM、比表面及孔隙度分析仪等方法对产物进行了表征. 结果表明, 粒径约为 4 nm 的金属性 Pt 较好地分散在 TNTs 及由纳米管转变而来、晶粒尺寸约为 8 nm 的锐钛矿相 TiO 晶粒表面, 复合物保留 2 2 了高于 216 m /g的比表面积. 光催化降解染料酸性红及亚甲基蓝的实验结果表明, 纯管有较好的吸附能力, 但是光 催化性能非常低, 经 120 ℃蒸气处理并负载贵金属 Pt 后光催化活性有了显著的提高 关 键 词: 纳米管; 蒸汽相水解; 二氧化钛; 锐钛矿相; Pt; 光催化 中图分类号: TB321 文献标识码: A Preparation of Pt-loaded TiO Nanotubes/Nanocrystals Composite Photocatalysts 2 and Their Photocatalytic Properties 1 1 2 1 1 YU Wei-Wei , ZHANG Qing-Hong , SHI Guo-Ying , LI Yao-Gang , WANG Hong-Zhi 1. State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China; 2. College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China Abstract: The composite photocatalysts combining high adsorptive capacity with enhanced photocatalytic effi- ciency are expected to be more efficient catalysts for the pollutant removal in the wastewater. TiO nanotubes 2 TNTs were synthesized via hydrothermal method using Degussa P25 titania as raw material. The Pt-loaded TiO nanotubes/nanocrystals composite photocatalysts Pt/TNNs were prepared via one-step synthesis method 2 involved the vapor phase hydrolysis setup, where TNTs were added into the ethanol solution containing chloro- platinic acid and citric acid as the reductant. During the water vapor treatment, some of the nanotubes were transformed into anatase TiO nanocrystals and a small amount of TNTs were kept as the tubular morphologies, 2thus the composite had a higher adsorptive capacity. The as-prepared samples were characterized by X-ray dif- fraction, transmission electron microscope and