超临界水中花生壳气化制氢催化剂的筛选与研究_裴爱霞.pdfVIP

42 7 西 安 交 通 大 学 学 报 Vol. 42 l 7 2008 7 JOURNAL OF XIcAN JIAOTONG UNIVERSITY Jul. 2008 , , , ( , 710049, ) : 在釜式反应装置上, 以原生生物质花生壳为原料M 为添加剂,对不同种 的催化剂在超 临界水中生物质催化气化制氢的影响进行了实验研究. 温度水平选择为400 e , 压力控制在22~ 24 MPa 范围内, 物料的质量分数为 10%, 催化剂包括 Zn l2K2 O3KOHNa2 O3NaOH LiOHa(OH)2RaneyONi橄榄石和白云石. 实验结果表明: 各种催化剂的催化效果有很大的区 别, 骨架催化剂RaneyONi 的大比表面积和特殊的电子层结构,使得生物质在超临界水中较低温度 条件下可以达到良好的气化效果,在所考察的几种 型催化剂中,RaneyONi 的产氢效率最高, 达到 281 03 g/kg,是一种极具潜力的超临界水生物质制氢催化剂. : 生物质;超临界水;气化; 制氢 : TK16 : A : 0253O987X(2008)07O0913O06 Research on Catalysts and Their Catalytic Characteristics for Hydrogen Production by Gasification of Peanut Shell in Supercritical Water PEI Aixia, ZHANG Rui, JIN Hui, GUO Liejin (State Key Laboratory of Multiphase Flow in Power Engineering, Xic an Jiaotong University, Xican 710049, hina) Abstr act: Experiments were conducted with an autoclave reactor to investigate the effects of cata2 lysts on the reaction. Peanut shell, mixed with sodium carboxymethylcellulose, was gasified at 400 e and in the range from 22 to 24 MPa with different catalysts, including Raney2Ni, a(OH)2 , Na2 O3 , K2 O3 , NaOH, KOH, LiOH, Zn l2 , dolomite and olivine. The results show that the biomass was gasified almost completely in the presence of Raney2Ni and the hydro2 gen production reached up to 281 03 g/kg. The highest activity can be attributed to the skeleton frame of Raney2Ni and the electronic shell ofNi. In addition, the related catalytic mechanism and kinetics were discussed based on the experiment results. Keywor ds: biomass; supercritical water; gasification; hydrogen production , , . ,. . , . [1O3], KOH K2 O3 ,, H2 O2 , ,, O , ,