海狗油功效成分的分子蒸馏分离的研究.pdfVIP

L043 海狗油功效成分的分子蒸馏分离研究 王淑华 许松林 应安国 （ 天津大学精馏技术国家工程中心，天津 00072） 摘 要 简要介绍了二十碳五烯酸EPA 、二十二碳六烯酸DHA和二十二碳五烯酸DPA等几种多不 饱和脂肪酸对人体的生理调节和保健作用，并指出了海狗油在制备不饱和脂肪酸时取代鱼油资源 的优势。本文研究了运用刮膜式分子蒸馏技术分离浓缩海狗油乙酯中EPA 、DHA和DPA 的研究。 考察了蒸馏温度、系统压力和操作级数等工艺参数对其总含量和收率的影响。研究结果表明，适 -1 -1 宜的操作条件为操作压力 0.4Pa，蒸馏温度 90-95℃，进料速率为 90ml·h ，刮膜器转速 125r·min ， 经过三级分子蒸馏操作即可将粗海狗油乙酯中功效成分的含量由 27.57 ％提高到 75.7 ％，收率为 66.5 ％。 关键词 海狗油 ω3 不饱和脂肪酸 分子蒸馏 功效成分 分离 中图分类号 文献表示码 文章编号 THE SEPARATION STUDY OF EFFECTIVE COMPOSITIONS IN SEAL OIL BY MOLECULAR DISTILLATION WANG Shuhua, XU Songlin and YING Anguo (National Engineering Research Center for Distillation Technology, Tianjin University, Tianjin, China, 300072) Abstract The function of EPA, DHA and DPA in polyunsaturated fatty acids on human body were simply introduced in the paper. On acquiring PUFA, seal oil has more advantages as raw material than others according to a comparison. The seal oil ethyl esters were separated by molecular distillation in this study. Operating parameters like distillation temperature, operating pressure and operating stages, the factors of them on sum contents and yield of EPA, DHA and DPA have been studied. The optimal conditions could be gotten from the experiments, including distillation temperature 90-95 ℃, operating pressure 0.4Pa, feed rate 90ml/h, rotor speed 125r/min, the sum contents of EPA, DHA and DPA can be increased from 27.57% to 75.7% after three stages, the yield is 66.5%, correspondingly. Key words seal oil, ω-3 PUFA, molecular di