碱激发碳酸盐矿胶凝材料硬化体结构地研究.pdfVIP

碱激发碳酸盐矿胶凝材料硬化体结构的研究 林坚钦 殷素红 余其俊 文梓芸 （华南理工大学材料科学与工程学院，特种功能材料教育部重点实验室，广州，510640 ） 摘 要：对碱激发碳酸盐矿胶凝材料（C体系）及碱激发碳酸盐矿－矿渣复合胶凝材料（CS体系）硬化体的反应产物、 微观形貌及孔隙溶液进行了研究。结果表明，同龄期时CS体系比C体系的反应产物更多，浆体结构更致密；两体系 产物的(Ca+Mg)/Si摩尔比不同；两体系孔溶液中Na+浓度高，CS体系SiO 浓度比C体系小一个数量级，且 3d时已很低， 2 C体系的SiO2浓度随龄期延长逐步降低。两体系硬化体结构的差异导致强度性能的不同，C体系的强度低，但随龄期 延长强度持续增长；CS体系的强度远高于C体系，且早期强度高。 关键词：碱激发碳酸盐矿；矿渣；硬化体结构；(Ca+Mg)/Si 摩尔比；孔隙溶液 中图分类号：TU528 ；TQ172 RESEARCH OF HARDENITE STRUCTURE OF ALKALI-ACTIVATED CARBONATITE CEMENTITIOUS MATERIAL LIN Jianqin, YIN Suhong, YU Qijun, WEN Ziyun (College of Materials Science and Engineering, South China University of Technology, Key Laboratory of Specially Functional Materials of Ministry of Education, Guangzhou, 510640, China ） Abstract: Reaction product, microstructure and pore solution of hardenite of alkali-activated carbonatite cementitious material (C system) and alkali-activated carbonatite-slag cementitious material (CS system) at different ages were studied in this research. The results show that CS system’s reaction product is more and paste structure is compacter than C system’s at the same age, the mol ratio of (Ca+Mg) to Si of the two systems’ product is no the same, the concentration of Na+ in pore solution of both systems is very high, the concentration of SiO2 in pore solution of CS system is far lower than C system and very low at 3 days, C system’s concentration of SiO2 is decreasing when curing age prolongs. The difference of two systems’ hardenite structure makes the difference of strength, the strength of C system is low, and increasing when curing age prolongs, CS system’s strength is far higher than C system’s and high at early age. Key words: alkali-activated carbonatite，slag，hardenite structure ，mol ratio of (Ca+Mg) to Si ，pore solution 近几年我们对碱激发碳酸盐矿胶