AuNPs-PNIPAM复合颗粒的制备及其温敏性质.pdfVIP

理化学学报(Wuli Huaxue Xuebao) December A cta Phys. Chim. Sin., 2008, 24(12) ：2159-2164 2159 [Article] AuNPs/PNIPAM 复合颗粒的制备及其温敏性质 彩云 翁晓磊 钱卫平 (东南大学生物科学与医学工程学院, 生 电子学国家重点实验室, 南京 210096) 摘要： 将金纳米颗粒(AuNPs)组装到聚N 异丙基丙烯酰胺(PNIPAM)水凝胶微球表面制备出AuNPs/PNIPAM 复合颗粒. 将PNIPAM 凝胶的温敏特性与AuNPs 的光学性质结合, 通过改变温度调节AuNPs 的局部表面等离 子共振(LSPR)吸收峰位置. 研究结果表明, 温度升高使AuNPs 的LSPR 吸收峰发生红移, 并且这种效应是可逆 的. 同时发现, AuNPs 的光学性质还可以作为表征PNIPAM 水凝胶微球温敏行为的一种手段. 利用透射电镜、紫 外 可见光谱仪及动态光散射仪对AuNPs/PNIPAM 复合颗粒的形貌、光学性质、粒径变化等进行了分析. 关键词： 金纳米颗粒; 聚N 异丙基丙烯酰胺; 温敏凝胶; 局部表面等离子共振 中图分类号： O648 Preparation and Thermoresponsive Properties of AuNPs/PNIPAM Composite Particles JIANG Cai Yun WENG Xiao Lei QIAN Wei Ping (State Key Laboratory of Bioelectronics, School of Biological Science and Medical Engineering, Southeast University, Nanji ng 210096, P. R. China) Abstract ： A new composite of Au nanoparticles (AuNPs) adsorbed on thermoresponsive poly(N isopropyl acrylamide) (PNIPAM) microgels that combines the thermoresponsive behavior of PNIPAM microgels with the optical properties of Au nanoparticles is reported . The LSPR (localized surface plasmon resonance) of the AuNPs could be changed by adjusting the temperature of the thermoresponsive PNIPAM microgels. An increase in temperature led to a red shift of the LSPR of the AuNPs and this change was found to be fully reversible. Optical properties of AuNPs were used to monitor the thermoresponsive behavior