干发酵对稻草结构及产沼气的影响.pdfVIP

中国环境科学 2011,31(3) ：417~422 China Environmental Science 干发酵对稻草结构及产沼气的影响 1,2 3* 1 3 3 1 梁越敢 ,郑 正 ,汪龙眠 ,罗兴章 ,张继彪 ,罗 艳 (1.南京大学环境学院,污染控制与资源化研究国家 重点实验室,江苏 南京 210093 ；2.安徽农业大学资源与环境学院,安徽 合肥 230036 ；3.复旦大学环境科学与工程 系,上海 200433) 摘要：为了防止稻草焚烧产生的环境污染,采用厌氧干发酵方式对稻草进行资源化处理.通过稻草元素的分析、X 射线衍射(XRD)及红外光 谱(FT-IR) 的分析,考察了干发酵及预处理对稻草结构的改变.结果表明,稻草干发酵 60d 单位挥发固体累积产气量 278.1mL/g (0 ℃),前 30d 产气占总产气量的 90.3%;XRD 显示稻草纤维晶体为纤维素Ⅰ型,堆沤预处理和厌氧发酵未改变纤维素的晶型,但略微增加纤维素的结晶 度;FT-IR 表明:堆沤预处理使聚糖脱聚、纤维素分子键氢键增强和木质素结构部分改变;发酵主要使聚糖脱聚与降解. 关键词：稻草；干发酵；结构变化；X 射线衍射分析；红外光谱分析 中图分类号：X 705 文献标识码：A 文章编号：1000-6923(2011)03-0417-06 Effect of dry digestion on structure changes and biogas production from rice straw. LIANG Yue-gan1,2, ZHENG 3* 1 3 3 1 Zheng , WANG Long-ming , LUO Xing-zhang , ZHANG Ji-biao , LUO Yan (1. State Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093, China ；2.School of the Resource and Environment, Anhui Agricultural University, Hefei 230036, China ；3.Department of Environmental Science and Engineering, Fudan University, Shanghai 200433, China). China Environmental Science, 2011,31(3)：417~422 Abstract ：In order to avoid the environmental pollution of open-field burning of rice straw, dry digestion of rice straw is an alternative measure which may produce methane. Composition and structure of raw and treated rice straw were mainly studied by the composition analysis, X-ray and FT-IR analysis, so as to investigate structure changes of rice straw during compost and dry digestion. The results showed that the cumulative biogas yield added up to 278.1mL/g VS added (0℃) during 60days dry digestion and the approximately 90.3% of the biogas yield was