模拟混凝土孔隙液中钢筋表面膜组成与腐蚀行为的关联.pdfVIP

℄ 47 ℄ 6 Vol.47 No.6 2011 6 ℄ 735—742 ACTA METALLURGICA SINICA Jun. 2011 pp.735–742  ∗ (, 361005) XPS , ,  . : . Cl− pH , Cl− pH , , ;  Fe2+ , Fe3+ . Cl− 0.6 mol/L pH 11.31 ,  , 0.24 mol/L NaNO2 . , , , Cl− O646 A 0412−1961(2011)06−0735−08 CORRELATION BETWEEN COMPOSITION OF REINFORCING STEEL SURFACE FILM AND STEEL CORROSION BEHAVIOR IN SIMULATED CONCRETE PORE SOLUTIONS CHEN Wen, DU Ronggui, HU Ronggang, SHI Haiyan, ZHU Yanfeng, LIN Changjian State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 Correspondent: DU Ronggui, professor, Tel: (0592)2189192, E-mail: rgdu@xmu.edu.cn Supported by National Natural Science Foundation of China (Nosand and National High Technology Research and Development Program of China (No.2009AA03Z327) Manuscript received 2011–01–24, in revised form 2011–03–31 ABSTRACT It is well known that reinforcing steel in concrete can be protected from corrosion by forming a compact passive film on its surface in a concrete pore solution with high alkalinity. The corrosion behavior of the steel is related to its passivation and depassivation. The pH value and the Cl− concentration in a concrete pore solution are of the most important parameters affecting the passivity of reinforcing steel in concrete. In the present work, XPS analysis, linear polarization and potentiodynamic anodic polarization tests were used to study the relationship bet