PET_PEN共混物的热分解行为及其动力学_闰明涛.pdfVIP

第27 卷　第1 期 河北大学学报(自然科学版) Vol.27 No.1 2007 年　1 月 Journal of Hebei Uni ersity (Natural Science Edition) Jan.2007 PET/PEN 共混物的热分解行为及其动力学 闰明涛, 王迎进, 姚晨光,高俊刚 (河北大学 化学与 境科学学院, 河北 保定　07 1002) 　　摘　要:研究了惰性气氛下聚对苯二甲酸乙二酯(PET )/聚对萘二甲酸乙二酯(PEN )共混物的非等温热 分解行为及其动力学.研究发现,不同PET/PEN 共混物的热降解为一个主要的热分解过程,热分解反应为 一级反应.随着共混物中PEN 质量分数的增加,共混物的起始分解温度逐渐升高,共混物的热稳定性逐渐提 高,而且共混物的热分解反应活化能也逐渐增加, 这是由于PEN 分子链中萘 的热分解温度比PET 中苯 高, 因此分子链的热稳定性比PET 要高.共混物中萘 的化学组成含量越高, 则热稳定性愈高. 关键词:聚对苯二甲酸乙二酯;聚对萘二甲酸乙二酯;热分解动力学 中图分类号:TQ 323.8　　　文献标识码:A 　　　文章编号:1000-1565(2007)01-0059-05 Thermal Degradation Kinetics of PET/PEN Blends RUN Ming-tao, WANG Ying-j in, YAO Chen-guang, GAO Jun-gang (College of Chemistry and En ironmental Science, Hebei Uni ersity, Baoding 071002, China) Abstract:The non-isothermal degradation processes of poly (ethylene terephthalate)(PET )and poly (ethy- lene 2,6-naphthalate)(PEN)blends w ere studied by using thermogra imetry (TG )analysis in nitrogen.The non-isothermal degradation of arious PET/PEN blends w ere found to be one-staged degradation processes and first order reaction .The PET/PEN blends with more PEN component exhibited w ith higher decomposed tem- perature than those with less PEN contents due to the naphthalene nucleus has a higher thermal stability than that of phenyl nucleus.The apparent acti ation energy (E )of blends is calculated by Ozawa method and the re- sults suggest that the blend with more content of PEN has a higher alue of E . Key words:poly (ethylene terephthalate);poly (ethylene 2,6-naphthalate);thermal degradation kinetics 高性能聚酯PEN 具有较高的阻隔性、较好的耐热性和力学性能,在PET 聚酯阻隔性和耐热性达不到要 求的应用领域, PEN 显示出卓越的性能.但其成本较高, 许多公司采用共混或共聚的方法用PEN 来改性 [ 1] [2-3] PET,从而得到优良性能的改性聚酯 .PEN 与PET 这2 种聚合物的物理共混物为不相容体系