3,5-二溴水杨醛-2-氨基吡啶Schiff碱-Eu3+-邻菲啰啉三元体系.docVIP

3,5-二溴水杨醛缩-2-氨基吡啶Schiff碱-Eu3+-邻菲啰啉三元体系在溶液中的荧光性质研究和应用 张立娟，，*，安玉刚 北京化工大学化工资源有效利用国家重点实验室，北京化工大学理学院，北京，100029 Email: zhouys@mail.buct.edu.cn 本文建立了一种测量微量Eu3+的高效、灵敏的荧光分析方法。在3,5-二溴水杨醛缩-2-氨基吡啶Schiff碱（HL）和Eu3+的乙腈溶液中加入第二配体邻菲啰啉(Phen)后，体系荧光强度显著增强。激发和发射波长分别为274 nm和617 nm。在最优测试条件下，得到Eu3+在1.0 ( 10-6 ~ 2.4 ( 10-5 mol(L-1浓度范围的工作曲线Fig.1, Eu3+检出限为0.43(10-9 mol(L-1。测定了其它稀土离子对Eu3+的最大干扰量，应用该方法对高纯Gd2O3中Eu3+的含量进行了样品分析，相对标准偏差在0.2%~1.54%范围内。研究了体系内的能量传递机理三元体系中Phen能量传递作用。 Fig.1. The working curve of Eu3+. Conditions:[HL]: 6 ( 10-6 mol(L-1; [Phen], 1.0 ( 10-4 mol(L-1 Schiff碱; 邻菲啰啉; Eu; 荧光分析法 参考文献： [1] Bnelli C.; Gatteschi D. Chem. Rev. 2002,102:2369. [2] Dang F.; Liu W.; Zheng J. Spectrochim. Acta, Part A, 2007, 67: 714. Enhanced fluorescence of 3, 5-dibromo-salicylaldehyde-2-aminopyfidine Schiff base-Eu3+ with 1,10-phenanthroline ternary system and its analytical application Lijuan Zhang, Xiaorui Zheng, Yunshan Zhou*, Yugang An State Key Laboratory of Chemical Resource Engineering, College of Science, Beijing University of Chemical Technology, Beijing 100029, P. R. China A sensitive fluorescence enhancement system was developed for the determination of Eu3+.The fluorescence intensity of 3,5-dibromo-salicylaldehyde-2-aminopyfidine Schiff base(HL)-Eu3+ was greatly enhanced by the addition of 1,10-phenanthroline(Phen) in the acetonitrile. The excitation and emission wavelengths were 274 nm and 617 nm, respectively. Under optimal conditions, the fluorescence intensities varied linearly with the concentration of Eu3+ in the range of 1.0 ( 10-6 ~ 2.4 ( 10-5 mol(L-1 with a detection limit of 0.43(10-9 mol(L-1 and the relative standard deviation in the range of 0.2%~1.54%. The interferences of some rare earth ions were described. This method can be applied satisfactorily to the determination of trace amounts of Eu3+ in a high purity Gd2O3 matrix. The mechanism of fluorexcence enhancement was studied and it was found that both Phen and HL can transfer energy to Eu3+ in the HL-Eu3+-Phen ternary syste